FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313308255> ?p ?o ?g. }

• W4313308255 endingPage "214983" @default.
• W4313308255 startingPage "214983" @default.
• W4313308255 abstract "The metal-catalyzed epoxidation of olefins is an important reaction in organic synthesis, as epoxides are useful intermediates for the production of bulk and fine chemicals. Molybdenum complexes are known as effective catalysts for selective epoxidation with alkyl hydroperoxides as oxidants. Very early on, it was recognized that molybdenum hexacarbonyl could be used directly as a catalyst precursor, being converted in situ to a soluble MoVI active species. In recent years this field has expanded greatly with the study of a wide range of group 6 carbonyl complexes as precursors to catalysts and/or functional metal oxides. In this review, pioneering work on the use of group 6 hexacarbonyls, mainly Mo(CO)6, as pre-catalysts is summarized, followed by a comprehensive analysis of recent research in which heteroleptic complexes of the type [Mo(CO)x(L)n] (x = 3 or 4; n = 1 or 3) and [MXm(CO)3(L)n] (M = Mo, W; X = halide; m = 1 or 2; n = 1 or 2) were employed, where L is a N-, O- or P-donor ligand. The topics covered include precursor synthesis and structural chemistry, solvent, oxidant and ligand effects, catalytic applications for the valorization of functionalized and nonfunctionalized olefins, catalyst activation and mechanistic studies. Current understanding about the oxidation of the heteroleptic Mo0/II complexes to oxomolybdenum complexes or hybrid materials is discussed, with a review of the behavior of these compounds as (pre)catalysts for homogeneous or heterogeneous olefin epoxidation." @default.
• W4313308255 created "2023-01-06" @default.
• W4313308255 creator A5007200893 @default.
• W4313308255 creator A5048643321 @default.
• W4313308255 creator A5085198184 @default.
• W4313308255 creator A5087409884 @default.
• W4313308255 date "2023-03-01" @default.
• W4313308255 modified "2023-09-26" @default.
• W4313308255 title "Group 6 carbonyl complexes of N,O,P-ligands as precursors of high-valent metal-oxo catalysts for olefin epoxidation" @default.
• W4313308255 cites W147744500 @default.
• W4313308255 cites W1508720996 @default.
• W4313308255 cites W1525757524 @default.
• W4313308255 cites W1912043436 @default.
• W4313308255 cites W1963703725 @default.
• W4313308255 cites W1967970061 @default.
• W4313308255 cites W1971451752 @default.
• W4313308255 cites W1971852816 @default.
• W4313308255 cites W1973447000 @default.
• W4313308255 cites W1973574118 @default.
• W4313308255 cites W1974505358 @default.
• W4313308255 cites W1975367910 @default.
• W4313308255 cites W1979080155 @default.
• W4313308255 cites W1979546891 @default.
• W4313308255 cites W1980153495 @default.
• W4313308255 cites W1982218880 @default.
• W4313308255 cites W1982775831 @default.
• W4313308255 cites W1983230556 @default.
• W4313308255 cites W1992071524 @default.
• W4313308255 cites W1993106862 @default.
• W4313308255 cites W1993909024 @default.
• W4313308255 cites W1998268770 @default.
• W4313308255 cites W2001958512 @default.
• W4313308255 cites W2002033554 @default.
• W4313308255 cites W2002196872 @default.
• W4313308255 cites W2005061076 @default.
• W4313308255 cites W2005061184 @default.
• W4313308255 cites W2005888010 @default.
• W4313308255 cites W2005998914 @default.
• W4313308255 cites W2007042812 @default.
• W4313308255 cites W2009097726 @default.
• W4313308255 cites W2009832356 @default.
• W4313308255 cites W2010569745 @default.
• W4313308255 cites W2015504903 @default.
• W4313308255 cites W2017299968 @default.
• W4313308255 cites W2018506301 @default.
• W4313308255 cites W2018684900 @default.
• W4313308255 cites W2019949527 @default.
• W4313308255 cites W2020504682 @default.
• W4313308255 cites W2024447680 @default.
• W4313308255 cites W2024859771 @default.
• W4313308255 cites W2027195373 @default.
• W4313308255 cites W2032295345 @default.
• W4313308255 cites W2033126110 @default.
• W4313308255 cites W2034567723 @default.
• W4313308255 cites W2041802869 @default.
• W4313308255 cites W2042472659 @default.
• W4313308255 cites W2042587232 @default.
• W4313308255 cites W2042664402 @default.
• W4313308255 cites W2045539127 @default.
• W4313308255 cites W2047113343 @default.
• W4313308255 cites W2047423445 @default.
• W4313308255 cites W2048156091 @default.
• W4313308255 cites W2049814916 @default.
• W4313308255 cites W2049952449 @default.
• W4313308255 cites W2050513185 @default.
• W4313308255 cites W2051258674 @default.
• W4313308255 cites W2053201843 @default.
• W4313308255 cites W2054073367 @default.
• W4313308255 cites W2058950523 @default.
• W4313308255 cites W2059008770 @default.
• W4313308255 cites W2063458315 @default.
• W4313308255 cites W2065010282 @default.
• W4313308255 cites W2067486404 @default.
• W4313308255 cites W2075849952 @default.
• W4313308255 cites W2082419650 @default.
• W4313308255 cites W2085510751 @default.
• W4313308255 cites W2089712543 @default.
• W4313308255 cites W2091328090 @default.
• W4313308255 cites W2091804821 @default.
• W4313308255 cites W2094004137 @default.
• W4313308255 cites W2095340325 @default.
• W4313308255 cites W2096517067 @default.
• W4313308255 cites W2100252231 @default.
• W4313308255 cites W2106442422 @default.
• W4313308255 cites W2111327244 @default.
• W4313308255 cites W2112057724 @default.
• W4313308255 cites W2112803065 @default.
• W4313308255 cites W2115798469 @default.
• W4313308255 cites W2119918474 @default.
• W4313308255 cites W2133215485 @default.
• W4313308255 cites W2151250132 @default.
• W4313308255 cites W2154853370 @default.
• W4313308255 cites W2166862648 @default.
• W4313308255 cites W2166994344 @default.
• W4313308255 cites W2171035155 @default.
• W4313308255 cites W2175965007 @default.
• W4313308255 cites W2253656646 @default.
• W4313308255 cites W2290179291 @default.

• next