Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313311932> ?p ?o ?g. }
- W4313311932 endingPage "2194" @default.
- W4313311932 startingPage "2183" @default.
- W4313311932 abstract "The revival of ternary halides Li-M-X (M = Y, In, Zr, etc.; X = F, Cl, Br) as solid-state electrolytes (SSEs) shows promise in realizing practical solid-state batteries due to their direct compatibility toward high-voltage cathodes and favorable room-temperature ionic conductivities. Most of the reported superionic halide SSEs have a structural pattern of [MCl6]x- octahedra and generate a tetrahedron-assisted Li+ ion diffusion pathway. Here, we report a new class of zeolite-like halide frameworks, SmCl3, for example, in which 1-dimensional channels are enclosed by [SmCl9]6- tricapped trigonal prisms to provide a short jumping distance of 2.08 Å between two octahedra for Li+ ion hopping. The fast Li+ diffusion along the channels is verified through ab initio molecular dynamics simulations. Similar to zeolites, the SmCl3 framework can be grafted with halide species to obtain mobile ions without altering the base structure, achieving an ionic conductivity over 10-4 S cm-1 at 30 °C with LiCl as the adsorbent. Moreover, the universality of the interface-bonding behavior and ionic diffusion in a class of framework materials is demonstrated. It is suggested that the ionic conductivity of the MCl3/halide composite (M = La-Gd) is likely in correlation with the ionic conductivity of the grafted halide species, interfacial bonding, and framework composition/dimensions. This work reveals a potential class of halide structures for superionic conductors and opens up a new frontier for constructing zeolite-like frameworks in halide-based materials, which will promote the innovation of superionic conductor design and contribute to a broader selection of halide SSEs." @default.
- W4313311932 created "2023-01-06" @default.
- W4313311932 creator A5005584237 @default.
- W4313311932 creator A5007672814 @default.
- W4313311932 creator A5008557264 @default.
- W4313311932 creator A5015251883 @default.
- W4313311932 creator A5019086334 @default.
- W4313311932 creator A5030743926 @default.
- W4313311932 creator A5033199641 @default.
- W4313311932 creator A5036700518 @default.
- W4313311932 creator A5037743899 @default.
- W4313311932 creator A5040303259 @default.
- W4313311932 creator A5043347975 @default.
- W4313311932 creator A5043896567 @default.
- W4313311932 creator A5051434566 @default.
- W4313311932 creator A5055317929 @default.
- W4313311932 creator A5061882657 @default.
- W4313311932 creator A5065728527 @default.
- W4313311932 creator A5066068469 @default.
- W4313311932 creator A5068472553 @default.
- W4313311932 creator A5070138234 @default.
- W4313311932 creator A5070818496 @default.
- W4313311932 creator A5081504089 @default.
- W4313311932 creator A5087765157 @default.
- W4313311932 creator A5090315068 @default.
- W4313311932 date "2022-12-30" @default.
- W4313311932 modified "2023-10-16" @default.
- W4313311932 title "Superionic Conducting Halide Frameworks Enabled by Interface-Bonded Halides" @default.
- W4313311932 cites W1999117785 @default.
- W4313311932 cites W2002662297 @default.
- W4313311932 cites W2032303555 @default.
- W4313311932 cites W2040106822 @default.
- W4313311932 cites W2046977550 @default.
- W4313311932 cites W2048686888 @default.
- W4313311932 cites W2052990284 @default.
- W4313311932 cites W2053146827 @default.
- W4313311932 cites W2070334583 @default.
- W4313311932 cites W2081957072 @default.
- W4313311932 cites W2088215070 @default.
- W4313311932 cites W2159270511 @default.
- W4313311932 cites W2167590372 @default.
- W4313311932 cites W2171716398 @default.
- W4313311932 cites W2593720910 @default.
- W4313311932 cites W2751261040 @default.
- W4313311932 cites W2755551054 @default.
- W4313311932 cites W2790074846 @default.
- W4313311932 cites W2891557444 @default.
- W4313311932 cites W2892260477 @default.
- W4313311932 cites W2936895644 @default.
- W4313311932 cites W2938929739 @default.
- W4313311932 cites W2971274177 @default.
- W4313311932 cites W2977858305 @default.
- W4313311932 cites W2982243128 @default.
- W4313311932 cites W2983762108 @default.
- W4313311932 cites W2996124024 @default.
- W4313311932 cites W3000010487 @default.
- W4313311932 cites W3013942423 @default.
- W4313311932 cites W3034202468 @default.
- W4313311932 cites W3035229048 @default.
- W4313311932 cites W3091305230 @default.
- W4313311932 cites W3092195113 @default.
- W4313311932 cites W3122364281 @default.
- W4313311932 cites W3138381431 @default.
- W4313311932 cites W3155679288 @default.
- W4313311932 cites W3158131203 @default.
- W4313311932 cites W3161617443 @default.
- W4313311932 cites W3167995151 @default.
- W4313311932 cites W3184400016 @default.
- W4313311932 cites W3196775087 @default.
- W4313311932 cites W4206527188 @default.
- W4313311932 cites W4220740341 @default.
- W4313311932 cites W4248933783 @default.
- W4313311932 doi "https://doi.org/10.1021/jacs.2c09446" @default.
- W4313311932 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36583711" @default.
- W4313311932 hasPublicationYear "2022" @default.
- W4313311932 type Work @default.
- W4313311932 citedByCount "5" @default.
- W4313311932 countsByYear W43133119322023 @default.
- W4313311932 crossrefType "journal-article" @default.
- W4313311932 hasAuthorship W4313311932A5005584237 @default.
- W4313311932 hasAuthorship W4313311932A5007672814 @default.
- W4313311932 hasAuthorship W4313311932A5008557264 @default.
- W4313311932 hasAuthorship W4313311932A5015251883 @default.
- W4313311932 hasAuthorship W4313311932A5019086334 @default.
- W4313311932 hasAuthorship W4313311932A5030743926 @default.
- W4313311932 hasAuthorship W4313311932A5033199641 @default.
- W4313311932 hasAuthorship W4313311932A5036700518 @default.
- W4313311932 hasAuthorship W4313311932A5037743899 @default.
- W4313311932 hasAuthorship W4313311932A5040303259 @default.
- W4313311932 hasAuthorship W4313311932A5043347975 @default.
- W4313311932 hasAuthorship W4313311932A5043896567 @default.
- W4313311932 hasAuthorship W4313311932A5051434566 @default.
- W4313311932 hasAuthorship W4313311932A5055317929 @default.
- W4313311932 hasAuthorship W4313311932A5061882657 @default.
- W4313311932 hasAuthorship W4313311932A5065728527 @default.
- W4313311932 hasAuthorship W4313311932A5066068469 @default.
- W4313311932 hasAuthorship W4313311932A5068472553 @default.
- W4313311932 hasAuthorship W4313311932A5070138234 @default.