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• W4313311939 abstract "This publication describes the application of Re2O7 in hexafluoroisopropanol (HFIP) for the activation of inert as well as electronically deactivated olefins to facilitate a challenging intramolecular hydroacyloxylation reaction. Both HFIP and an internal carboxy group have been proven to be crucial for the successful implementation of this transformation; these are proposed to assist the formation and stabilization of the key cationic intermediate via hydrogen-bonding interactions with perrhenate anion (ReO4-)." @default.
• W4313311939 created "2023-01-06" @default.
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• W4313311939 date "2022-12-30" @default.
• W4313311939 modified "2023-10-05" @default.
• W4313311939 title "Re₂O₇/HReO₄ Mediated Intramolecular Hydroacyloxylation of Unactivated Alkenes: A Dual Hydrogen-Bonding Effect" @default.
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• W4313311939 doi "https://doi.org/10.1021/acs.orglett.2c03846" @default.
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• W4313311939 hasPublicationYear "2022" @default.
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