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- W4313332924 abstract "Microphase separation in polymeric systems provides a bottom-up strategy to fabricate nanostructures. Polymers that are reported to undergo microphase separation usually include block copolymers or polyelectrolytes. Neutral homopolymers, which are comparatively easy to synthesize, are thought to be incapable of microphase separation. Here, using a minimal model that accounts for ion solvation, we show that microphase separation is possible in neutral homopolymer blends with sufficient dielectric contrast, upon a tiny amount of salt-doping. The driving force for the microphase separation is the competition between selective ion solvation, which places smaller ions in domains with higher dielectric constant, and the propensity for local charge neutrality to decrease the electrostatic energy. The compromise is an emergent length over which microphase separation occurs and ions are selectively solvated. The factors affecting such competitions are explored, including ion solvation radii, dielectric contrast, and polymer fraction, which point to directions for observing this behavior experimentally. These findings suggest a low-cost and facile alternative to produce microphase separation, which may be exploited in advanced material design and preparation." @default.
- W4313332924 created "2023-01-06" @default.
- W4313332924 creator A5044375653 @default.
- W4313332924 creator A5071678608 @default.
- W4313332924 date "2022-12-29" @default.
- W4313332924 modified "2023-09-29" @default.
- W4313332924 title "Microphase Separation in Neutral Homopolymer Blends Induced by Salt-Doping" @default.
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- W4313332924 doi "https://doi.org/10.1021/acs.macromol.2c02198" @default.
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