FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313334537> ?p ?o ?g. }

• W4313334537 endingPage "112574" @default.
• W4313334537 startingPage "112574" @default.
• W4313334537 abstract "This work develops a detailed chemical kinetic model for Polycyclic Aromatic Hydrocarbon (PAH) chemistry that builds on a chemical model for gasoline surrogates by Cai et al. [Proc. Combust. Inst. 37 (2019) 639–647]. Informed by ab-initio and experimental studies, the model development emphasizes the prediction of soot precursors starting from C3H4 isomers up to the size of acepyrene. The proposed model was validated against experimental measurements from 79 publications, including ignition delay times, laminar burning velocities, and speciation data for several fuels in various conditions. A validation against measured peak mole fractions from 31 counterflow flames demonstrates an average prediction error of aromatic species up to the size of acenaphthalene below a factor of three. Additionally, the effects of experimental uncertainty are quantitatively discussed by computing confidence intervals for the true model prediction error. The formation of two-ring aromatic species is often still considered poorly understood. Accordingly, special attention is given to the formation of indene and naphthalene. Reaction flux analyses based on rigorously defined species selection criteria reveal that indene formation pathways are initiated by reactions of phenyl and benzyl and described by the reaction kinetics from theoretical calculations. In contrast, naphthalene formation is dominated by more uncertain pathways relying on estimated rates that are initiated by reactions of benzene and fulvenallenyl. Five-member rings on the periphery of PAH species and soot particles play a crucial role in recent experimental and theoretical studies. Therefore, this work investigates acenaphthene and other C12H8 isomers. The most abundant C12H8 isomers are acenaphthene, 1-ethynylnaphthalene, and 2-ethynylnaphthalene, and their respective concentrations are predicted to be similar in many flames. Furthermore, reaction flux analyses show that their formation is dominated by HACA routes starting from naphthalene." @default.
• W4313334537 created "2023-01-06" @default.
• W4313334537 creator A5011538465 @default.
• W4313334537 creator A5048936220 @default.
• W4313334537 creator A5063422746 @default.
• W4313334537 date "2022-12-01" @default.
• W4313334537 modified "2023-10-18" @default.
• W4313334537 title "A detailed kinetic model for aromatics formation from small hydrocarbon and gasoline surrogate fuel combustion" @default.
• W4313334537 cites W1491187441 @default.
• W4313334537 cites W1508604947 @default.
• W4313334537 cites W1559849469 @default.
• W4313334537 cites W1560749659 @default.
• W4313334537 cites W1921935873 @default.
• W4313334537 cites W1964818722 @default.
• W4313334537 cites W1966281189 @default.
• W4313334537 cites W1967474034 @default.
• W4313334537 cites W1969607870 @default.
• W4313334537 cites W1969643122 @default.
• W4313334537 cites W1969770822 @default.
• W4313334537 cites W1970781172 @default.
• W4313334537 cites W1971011913 @default.
• W4313334537 cites W1971056360 @default.
• W4313334537 cites W1971455864 @default.
• W4313334537 cites W1971801881 @default.
• W4313334537 cites W1974265702 @default.
• W4313334537 cites W1974425924 @default.
• W4313334537 cites W1974705036 @default.
• W4313334537 cites W1975147762 @default.
• W4313334537 cites W1975150576 @default.
• W4313334537 cites W1978042691 @default.
• W4313334537 cites W1981537309 @default.
• W4313334537 cites W1982232469 @default.
• W4313334537 cites W1983382715 @default.
• W4313334537 cites W1984532190 @default.
• W4313334537 cites W1985076507 @default.
• W4313334537 cites W1985713999 @default.
• W4313334537 cites W1985729863 @default.
• W4313334537 cites W1986659293 @default.
• W4313334537 cites W1987583730 @default.
• W4313334537 cites W1987948383 @default.
• W4313334537 cites W1990391639 @default.
• W4313334537 cites W1991424987 @default.
• W4313334537 cites W1992516739 @default.
• W4313334537 cites W1993146587 @default.
• W4313334537 cites W1993269755 @default.
• W4313334537 cites W1993786999 @default.
• W4313334537 cites W1996163919 @default.
• W4313334537 cites W1996421443 @default.
• W4313334537 cites W1996648756 @default.
• W4313334537 cites W1996789987 @default.
• W4313334537 cites W2001359264 @default.
• W4313334537 cites W2003057271 @default.
• W4313334537 cites W2003603101 @default.
• W4313334537 cites W2003767109 @default.
• W4313334537 cites W2004787016 @default.
• W4313334537 cites W2005535756 @default.
• W4313334537 cites W2005834079 @default.
• W4313334537 cites W2006103943 @default.
• W4313334537 cites W2007149509 @default.
• W4313334537 cites W2007582143 @default.
• W4313334537 cites W2013717277 @default.
• W4313334537 cites W2014149760 @default.
• W4313334537 cites W2015064849 @default.
• W4313334537 cites W2017743028 @default.
• W4313334537 cites W2018130294 @default.
• W4313334537 cites W2019233618 @default.
• W4313334537 cites W2019564537 @default.
• W4313334537 cites W2020413489 @default.
• W4313334537 cites W2021270343 @default.
• W4313334537 cites W2022127168 @default.
• W4313334537 cites W2022259852 @default.
• W4313334537 cites W2022463942 @default.
• W4313334537 cites W2022666944 @default.
• W4313334537 cites W2022809497 @default.
• W4313334537 cites W2024747980 @default.
• W4313334537 cites W2025050957 @default.
• W4313334537 cites W2025796240 @default.
• W4313334537 cites W2026139312 @default.
• W4313334537 cites W2027362683 @default.
• W4313334537 cites W2028499012 @default.
• W4313334537 cites W2030076618 @default.
• W4313334537 cites W2031981779 @default.
• W4313334537 cites W2032009542 @default.
• W4313334537 cites W2033242970 @default.
• W4313334537 cites W2034379883 @default.
• W4313334537 cites W2036153030 @default.
• W4313334537 cites W2036295404 @default.
• W4313334537 cites W2036860428 @default.
• W4313334537 cites W2036959633 @default.
• W4313334537 cites W2036979176 @default.
• W4313334537 cites W2041188874 @default.
• W4313334537 cites W2042019106 @default.
• W4313334537 cites W2042760042 @default.
• W4313334537 cites W2043332256 @default.
• W4313334537 cites W2045847248 @default.
• W4313334537 cites W2046909164 @default.
• W4313334537 cites W2047048358 @default.
• W4313334537 cites W2047484948 @default.

• next