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- W4313347105 abstract "Catalytic (3+1)- and (3+3)-cycloaddition reactions involving metal vinylcarbene intermediates offer viable alternatives to (2+2)- and (4+2)-processes that produce four- and six-membered ring products. Access to chiral heterocyclic compounds with high degrees of enantiocontrol is achieved under mild conditions with the use of modest amounts of transition metal catalysts and easily accessible chiral ligands. Electron-donating groups at the beta position of alpha-diazovinyl vinylcarbene precursors facilitate cycloaddition, and donor–acceptor cyclopropenes are often reaction intermediates." @default.
- W4313347105 created "2023-01-06" @default.
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- W4313347105 date "2022-01-01" @default.
- W4313347105 modified "2023-10-17" @default.
- W4313347105 title "(3+1)- and (3+3)-Cycloadditions" @default.
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- W4313347105 doi "https://doi.org/10.1016/b978-0-32-390644-9.00040-8" @default.
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