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- W4313362298 abstract "For the fast and simple sensing of the arsenic drug roxarsone (ROX), the development of a glassy carbon electrode (GCE) modified with cationic surfactant (cetyltrimethylammonium bromide, CTAB) material is critical. The CTAB-modified glassy carbon electrode, in contrast to the unmodified one, showed excellent behavior for electrochemical reduction of ROX using cyclic voltammetry (CV) and square-wave adsorptive stripping voltammetry (SWAdSV) techniques. CV studies reveal an irreversible reduction process of NO2 to NH–OH in the ROX molecule in NaAc–HAc buffer (pH = 5.6). The electrode material was characterized using CV and electrochemical impedance spectroscopy. The experiments show that the surfactant-modified material has faster electron transfer and a higher active surface area, and permits a diffusion–adsorption-controlled process. After optimization, the SWAdSV procedure with GCE/CTAB has linear ranges of 0.001–0.02 and 0.02–20 µM, and a detection limit of 0.13 nM. Furthermore, the procedure successfully determined roxarsone in river water samples." @default.
- W4313362298 created "2023-01-06" @default.
- W4313362298 creator A5072480692 @default.
- W4313362298 creator A5079283758 @default.
- W4313362298 date "2022-12-30" @default.
- W4313362298 modified "2023-10-05" @default.
- W4313362298 title "Glassy Carbon Modified with Cationic Surfactant (GCE/CTAB) as Electrode Material for Fast and Simple Analysis of the Arsenic Drug Roxarsone" @default.
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- W4313362298 doi "https://doi.org/10.3390/ma16010345" @default.
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