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• W4313367199 abstract "Adsorption of chiral molecules on chiral surfaces implies diastereomerism, evident in the adoption of distinct adsorption geometries. We show here that this diastereomerism produces a signature in the motion of chiral molecules desorbing from a chiral surface. The rotations of S- and R-alanine molecules are analyzed upon desorption from R-Cu{531} using first-principles molecular dynamics simulations. S-Ala molecules exhibit a larger angular momentum, with a clear preference for one rotational sense, whereas no such preference is observed for R-Ala molecules upon desorption from this surface. These trends would be reversed for desorption from the S-Cu{531} surface. Possible applications include chiral separation techniques and enantiospecific sensors." @default.
• W4313367199 created "2023-01-06" @default.
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• W4313367199 date "2022-12-30" @default.
• W4313367199 modified "2023-09-25" @default.
• W4313367199 title "Dynamic Diastereomerism on Chiral Surfaces" @default.
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• W4313367199 doi "https://doi.org/10.1021/acs.jpcc.2c06351" @default.
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