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• W4313372251 endingPage "120518" @default.
• W4313372251 startingPage "120518" @default.
• W4313372251 abstract "The pyrolysis kinetics of cellulosic fibres, a natural cotton yarn (NCY) and a mercerized cotton yarn (MCY), has been explored with a modified first order global analysis method (FOG), via a series of non-isothermal experiments, using thermogravimetric analysis (TGA). The modified FOG analysis routine was developed to overcome discrepancy in heating rate and the difference between exact results and approximations in integrals. The intrinsic pyrolysis activation energy, with temperature range tending to zero, was found to be independent of heating rate and approximation used, giving average values of 153 ± 2 kJ/mol for NCY and 192 ± 7 kJ/mol for MCY. This proves the applicability of the reported analysis routine under the conducted TGA measurements. The reasons for different values were hypothesized to be the difference in chemical composition and crystalline structure. The findings provide a new approach in the investigation on pyrolysis kinetics of biomass and factors impacting their pyrolytic behaviour." @default.
• W4313372251 created "2023-01-06" @default.
• W4313372251 creator A5032787316 @default.
• W4313372251 creator A5061499154 @default.
• W4313372251 creator A5069216480 @default.
• W4313372251 date "2023-04-01" @default.
• W4313372251 modified "2023-09-26" @default.
• W4313372251 title "Pyrolysis activation energy of cellulosic fibres investigated by a method derived from the first order global model" @default.
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• W4313372251 doi "https://doi.org/10.1016/j.carbpol.2022.120518" @default.
• W4313372251 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36737212" @default.
• W4313372251 hasPublicationYear "2023" @default.
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