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- W4313372888 abstract "Abstract A simple, metal‐free, and green approach has been established for N−H functionalization of sulfoximines under mild reaction conditions to offer sulfoximinated‐oxime conjugates. The reaction works well in EtOH at room temperature and proceeds smoothly without using any base or expensive ligands. This protocol has been applied on various aryl‐, heteroaryl‐ sulfoximines as well as on variety of chloro‐oximes. Both the substrates tolerated a wide range of functional groups, resulting in good to excellent yields. It can serve as a directing group in organic synthesis, as a precursor or building block, demonstrating the product's applicability and importance in the field. The applications of the protocol have been demonstrated in the sulfoximination of some natural products. This strategy could be useful in drug discovery or medicinal chemistry for fine‐tuning the physicochemical properties of natural product scaffolds or lead candidates." @default.
- W4313372888 created "2023-01-06" @default.
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- W4313372888 date "2022-12-22" @default.
- W4313372888 modified "2023-09-26" @default.
- W4313372888 title "Green Approach for N−H Functionalization of Sulfoximines: An Access to Sulfoximinated‐Oxime Conjugates" @default.
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- W4313372888 doi "https://doi.org/10.1002/ejoc.202201375" @default.
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