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- W4313379660 endingPage "297" @default.
- W4313379660 startingPage "293" @default.
- W4313379660 abstract "A sustainable method for converting terminal alkynes into their corresponding carboxylic acids is reported using synthetic electrolysis in an undivided cell at room temperature. This protocol, avoiding transition metal catalysis and stoichiometric chemical oxidants, tolerates a variety of aryl, heteroaryl, and alkyl akynes. Preliminary mechanistic studies demonstrate that sodium nitrite serves a triple role as the electrolyte, nitryl radical precursor, and a nitrosating reagent." @default.
- W4313379660 created "2023-01-06" @default.
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- W4313379660 date "2023-01-01" @default.
- W4313379660 modified "2023-10-18" @default.
- W4313379660 title "Electrochemical Oxidative Cleavage of Alkynes to Carboxylic Acids" @default.
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- W4313379660 doi "https://doi.org/10.1021/acs.orglett.2c04204" @default.
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