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- W4313397535 endingPage "123040" @default.
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- W4313397535 abstract "Two iridium(III) complexes [(L1)2Ir(tpip)] (Ir1, L1 = 6-phenylnicotinaldehyde), [(L2)2Ir(tpip)] (Ir2, L2 = 6-(4-(trifluoromethyl)phenyl)nicotinaldehyde), bearing tetraphenylimidodiphosphinate (tpip) ancillary ligand, were developed as efficient luminescent sensor for the detection of Zn2+. Ir1 and Ir2 exhibited broad emission bands peaking at 613 nm and 603 nm with PLQY of 0.32 and 0.57 and lifetimes of 1.8 and 1.3 μs, respectively. They showed excellent response to Zn2+ with a high sensitivity and selectivity, low detection limit on the order of 10−7 M and short response time on seconds in solution. Such an outstanding detection was based on significant blue shifts of their emissions. Nanofibers with these complexes were fabricated by electrospinning to realize the on-site detection of Zn2+ in solid-phase with similar colorimetric changes of their phosphorescence as in solution." @default.
- W4313397535 created "2023-01-06" @default.
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- W4313397535 date "2023-03-01" @default.
- W4313397535 modified "2023-10-15" @default.
- W4313397535 title "Selective and sensitive detection of Zn(II) in solution and nanofibers using phosphorescent iridium(III) complexes" @default.
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- W4313397535 doi "https://doi.org/10.1016/j.seppur.2022.123040" @default.
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