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- W4313404730 abstract "Abstract Four o ‐carborane‐based aggregation‐induced emission molecules with ultra‐large Stokes shifts were designed and synthesized. To explore the origin of the ultra‐large Stokes shifts (Δλ ≈ 268–294 nm) of the four target molecules, a new molecule named CZ ‐ Ph ‐ PO was synthesized by replacing the o ‐carborane unit in CZ ‐ CB ‐ PO with a benzene ring. It was found that the ultra‐large Stokes shift was the result of the combined action of diphenylphosphinyl and o ‐carborane, in which o ‐carborane was the key group. In addition, combined with the single crystal structure analysis, the effect of halogens on molecular photophysical properties was investigated. Our work provides a reference for the design and synthesis of o ‐carborane‐based fluorescent molecules with ultra‐large Stokes shifts." @default.
- W4313404730 created "2023-01-06" @default.
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- W4313404730 date "2023-01-02" @default.
- W4313404730 modified "2023-10-12" @default.
- W4313404730 title "Synthesis and Characterization of New <i>o</i>‐Carboranes‐Based Aggregation‐Induced Emission Molecules with Ultra‐Large Stokes Shift" @default.
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- W4313404730 doi "https://doi.org/10.1002/slct.202204063" @default.
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