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- W4313406588 abstract "The development of photocaged glutamic acid (Glu) contributes to the time-resolved control of peptide and protein activities. Here, we efficiently synthesized the Glu with the side chain modified by photosensitive p-methoxyphenacyl group. This photocaged Glu can be introduced into peptide through standard 9‑fluorenylmethoxycarbonyl (Fmoc) solid phase peptide synthesis (SPPS), and can be re-exposed the Glu side-chain carboxy group by removing the photosensitive group under light irradiation. We prepared caged Endothelin-1 (ET-1) analogues with p-methoxyphenacyl-modified Glu and successfully achieved decaging." @default.
- W4313406588 created "2023-01-06" @default.
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- W4313406588 date "2023-02-01" @default.
- W4313406588 modified "2023-10-18" @default.
- W4313406588 title "Fmoc-SPPS-compatible p-methoxyphenacyl-modified glutamic for the synthesis of photocaged peptides" @default.
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- W4313406588 doi "https://doi.org/10.1016/j.tetlet.2023.154339" @default.
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