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• W4313420949 abstract "In this study, TiO2 was substituted as a nucleating agent to apply CaO–Al2O3–SiO2–ZnO (CASZ)-based glass to a high-hardness crystallized glaze, and the crystallization behavior and hardness of the glaze were observed with respect to the amount of TiO2 substitution. X-ray diffraction and scanning electron microscopy analyses revealed that as the TiO2 substitution increased, a titanite crystal phase was formed in the existing anorthite crystal phase, and the crystallinity of the glaze rapidly increased. In particular, the highest crystallinity of 83.8% was observed for 12.5 wt% TiO2 substitution. The activation energy and Avrami exponent (n) of the glaze were calculated via non-isothermal analysis using differential thermal analysis, and surface crystallization behavior of n ≤ 2.5 was observed for all mixing ratios. The density of the glaze increased from 2.33 to 2.80 g cm−3 as the TiO2 substitution increased. The hardness of the glaze showed the lowest value (3.12 GPa) for the sample without TiO2 substitution and increased rapidly to 6.33 GPa or higher in the TiO2 substitution specimens." @default.
• W4313420949 created "2023-01-06" @default.
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• W4313420949 date "2023-05-01" @default.
• W4313420949 modified "2023-09-23" @default.
• W4313420949 title "Effect of TiO2 content on crystallization behavior of CaO–Al2O3–SiO2–ZnO glass-ceramic glaze" @default.
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• W4313420949 doi "https://doi.org/10.1016/j.ceramint.2022.12.245" @default.
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