FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313431162> ?p ?o ?g. }

• W4313431162 endingPage "121006" @default.
• W4313431162 startingPage "121006" @default.
• W4313431162 abstract "We present results from a molecular dynamics study of the melting behavior of gas hydrates with empty cages under the specified overheating driving force, to understand how the melting process is dominated by thermodynamics and kinetics, respectively. The melting point of methane hydrates in different motif (cage occupancy and empty cage distribution) was determined firstly by direct simulations, and then the effects of overheating driving force, cage occupancy and empty cage distribution on the melting rate and mechanism were explored. Our results show that the induction time of melting has an Arrhenius relation with the overheating, and the activation energy is used for the distortion of the hydrate skeleton, which is independent of whether the cage is filled or not. The melting of hydrate can be divided into linear stage and final stage. The melting rate increases with the increase of overheating and the decrease of occupancy. In the linear stage, the empty and the filled cages are melted at multiple sites simultaneously if the empty cage distribution is separated, whereas the empty cage is rapidly melted from a single site for the system with concentrated empty cages. The phenomenological equation we proposed can be used to describe the influence of the real-time change of the occupancy and the empty cage distribution on the melting rate and mechanism. With the decrease of the size of guest molecules, the hydrate cage changes from filled-like to empty-like through a multi occupied intermediate state. The species boundary of Lennard-Jones guest molecules that can form empty-like cages is given." @default.
• W4313431162 created "2023-01-06" @default.
• W4313431162 creator A5070784105 @default.
• W4313431162 creator A5073501391 @default.
• W4313431162 creator A5086570255 @default.
• W4313431162 date "2023-01-01" @default.
• W4313431162 modified "2023-09-27" @default.
• W4313431162 title "The melting kinetics of gas hydrate with different cage occupancy and empty cage distribution" @default.
• W4313431162 cites W1551238254 @default.
• W4313431162 cites W1780326183 @default.
• W4313431162 cites W1976329114 @default.
• W4313431162 cites W1977590672 @default.
• W4313431162 cites W1978192002 @default.
• W4313431162 cites W1985272737 @default.
• W4313431162 cites W1991123780 @default.
• W4313431162 cites W1998013140 @default.
• W4313431162 cites W2000456051 @default.
• W4313431162 cites W2003045925 @default.
• W4313431162 cites W2018095938 @default.
• W4313431162 cites W2019124976 @default.
• W4313431162 cites W2019465613 @default.
• W4313431162 cites W2024336205 @default.
• W4313431162 cites W2031107710 @default.
• W4313431162 cites W2036520001 @default.
• W4313431162 cites W2042831386 @default.
• W4313431162 cites W2044084561 @default.
• W4313431162 cites W2048918625 @default.
• W4313431162 cites W2048933899 @default.
• W4313431162 cites W2069042781 @default.
• W4313431162 cites W2085039454 @default.
• W4313431162 cites W2085361134 @default.
• W4313431162 cites W2102455575 @default.
• W4313431162 cites W2106140689 @default.
• W4313431162 cites W2117581516 @default.
• W4313431162 cites W2324120681 @default.
• W4313431162 cites W2326611319 @default.
• W4313431162 cites W2327642267 @default.
• W4313431162 cites W2328965999 @default.
• W4313431162 cites W2416284953 @default.
• W4313431162 cites W2523208617 @default.
• W4313431162 cites W2792913748 @default.
• W4313431162 cites W2802247427 @default.
• W4313431162 cites W2802593548 @default.
• W4313431162 cites W2885883550 @default.
• W4313431162 cites W2912563828 @default.
• W4313431162 cites W2933967387 @default.
• W4313431162 cites W3115023950 @default.
• W4313431162 cites W3175401845 @default.
• W4313431162 cites W3175495115 @default.
• W4313431162 cites W3212986071 @default.
• W4313431162 cites W4205545958 @default.
• W4313431162 cites W4206311844 @default.
• W4313431162 cites W4206579343 @default.
• W4313431162 cites W4206677916 @default.
• W4313431162 cites W4285601378 @default.
• W4313431162 doi "https://doi.org/10.1016/j.molliq.2022.121006" @default.
• W4313431162 hasPublicationYear "2023" @default.
• W4313431162 type Work @default.
• W4313431162 citedByCount "0" @default.
• W4313431162 crossrefType "journal-article" @default.
• W4313431162 hasAuthorship W4313431162A5070784105 @default.
• W4313431162 hasAuthorship W4313431162A5073501391 @default.
• W4313431162 hasAuthorship W4313431162A5086570255 @default.
• W4313431162 hasConcept C100402318 @default.
• W4313431162 hasConcept C114614502 @default.
• W4313431162 hasConcept C121332964 @default.
• W4313431162 hasConcept C147597530 @default.
• W4313431162 hasConcept C147789679 @default.
• W4313431162 hasConcept C148898269 @default.
• W4313431162 hasConcept C159985019 @default.
• W4313431162 hasConcept C160272327 @default.
• W4313431162 hasConcept C178790620 @default.
• W4313431162 hasConcept C185592680 @default.
• W4313431162 hasConcept C192562407 @default.
• W4313431162 hasConcept C2778284599 @default.
• W4313431162 hasConcept C2781060337 @default.
• W4313431162 hasConcept C2985276288 @default.
• W4313431162 hasConcept C33923547 @default.
• W4313431162 hasConcept C59593255 @default.
• W4313431162 hasConcept C62520636 @default.
• W4313431162 hasConcept C86183883 @default.
• W4313431162 hasConcept C95121573 @default.
• W4313431162 hasConcept C97355855 @default.
• W4313431162 hasConceptScore W4313431162C100402318 @default.
• W4313431162 hasConceptScore W4313431162C114614502 @default.
• W4313431162 hasConceptScore W4313431162C121332964 @default.
• W4313431162 hasConceptScore W4313431162C147597530 @default.
• W4313431162 hasConceptScore W4313431162C147789679 @default.
• W4313431162 hasConceptScore W4313431162C148898269 @default.
• W4313431162 hasConceptScore W4313431162C159985019 @default.
• W4313431162 hasConceptScore W4313431162C160272327 @default.
• W4313431162 hasConceptScore W4313431162C178790620 @default.
• W4313431162 hasConceptScore W4313431162C185592680 @default.
• W4313431162 hasConceptScore W4313431162C192562407 @default.
• W4313431162 hasConceptScore W4313431162C2778284599 @default.
• W4313431162 hasConceptScore W4313431162C2781060337 @default.
• W4313431162 hasConceptScore W4313431162C2985276288 @default.
• W4313431162 hasConceptScore W4313431162C33923547 @default.

• next