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- W4313442893 endingPage "232581" @default.
- W4313442893 startingPage "232581" @default.
- W4313442893 abstract "Ba0.6La0.4F2.4 (BLF) is one of the promising candidates for solid-state electrolytes in fluoride-ion batteries owing to the wide electrochemical potential window. Compared with a BLF single crystal, the microstructure-modified BLF polycrystals by mechanochemical synthesis have improved the F− ion conductivity. However, the fundamental mechanism of the F− ion conductivity enhancement is still unclear because of the lack of structural and chemical analysis at the atomic level. Here, we investigate the microstructure of the mechanochemically synthesized BLF, using atomic-resolution scanning transmission electron microscopy combined with electron energy-loss spectroscopy. We find that the La-rich tysonite nano-precipitates are formed in the BLF fluorite matrix. The observed unique microstructure in BLF realized by mechanochemical synthesis would be the origin of the F− ion conductivity enhancement." @default.
- W4313442893 created "2023-01-06" @default.
- W4313442893 creator A5025115942 @default.
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- W4313442893 date "2023-02-01" @default.
- W4313442893 modified "2023-10-03" @default.
- W4313442893 title "Formation of La-rich tysonite nano-precipitates in fluorite Ba0.6La0.4F2.4" @default.
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- W4313442893 doi "https://doi.org/10.1016/j.jpowsour.2022.232581" @default.
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