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- W4313443000 abstract "The photocatalytic reduction of carbon dioxide to carbon monoxide with three new Ni(II)-bipyridine complexes, Ni-1 ([NiCl2(4,4′-dichloro-2,2′-bipyridine)2]), Ni-2 ([NiCl2(4,4′-dibromo-2,2′-bipyridine)2]), and Ni-3 ([NiCl2(4,4′-diphenyl-2,2′-bipyridine)2]), was studied in this work. The catalysts were applied in a mixture of acetonitrile and water, and tris(bipyridine)ruthenium(II) chloride was used as a photosensitizer in the presence of 1-benzyl-1,4-dihydronicotinamide as electron donor. Under visible-light irradiation, Ni-1 showed higher catalytic performance compared to conventional homogenous Ni-bipyridine catalysts, which was reasonably explained by high-resolution mass spectrometry and density functional theory investigations." @default.
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- W4313443000 date "2023-02-01" @default.
- W4313443000 modified "2023-10-14" @default.
- W4313443000 title "Photocatalytic reduction of CO2 to CO using nickel(II)-bipyridine complexes with different substituent groups as catalysts" @default.
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- W4313443000 doi "https://doi.org/10.1016/j.jcou.2022.102385" @default.
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