Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313446518> ?p ?o ?g. }
- W4313446518 endingPage "1102" @default.
- W4313446518 startingPage "1097" @default.
- W4313446518 abstract "Water is ubiquitous in olefin metathesis, at levels ranging from contaminant to cosolvent. It is also non-benign. Water-promoted catalyst decomposition competes with metathesis, even for robust ruthenium catalysts. Metathesis is hence typically noncatalytic for demanding reactions in water-rich environments (e.g., chemical biology), a challenge as the Ru decomposition products promote unwanted reactions such as DNA degradation. To date, only the first step of the decomposition cascade is understood: catalyst aquation. Here we demonstrate that the aqua species dramatically accelerate both β-elimination of the metallacyclobutane intermediate and bimolecular decomposition of four-coordinate [RuCl(H2O)n(L)(=CHR)]Cl. Decomposition can be inhibited by blocking aquation and β-elimination." @default.
- W4313446518 created "2023-01-06" @default.
- W4313446518 creator A5010060889 @default.
- W4313446518 creator A5056827531 @default.
- W4313446518 date "2023-01-03" @default.
- W4313446518 modified "2023-09-26" @default.
- W4313446518 title "Water-Accelerated Decomposition of Olefin Metathesis Catalysts" @default.
- W4313446518 cites W1545004059 @default.
- W4313446518 cites W1556962064 @default.
- W4313446518 cites W1855919732 @default.
- W4313446518 cites W1966857335 @default.
- W4313446518 cites W1968505735 @default.
- W4313446518 cites W1973818536 @default.
- W4313446518 cites W1991869994 @default.
- W4313446518 cites W1996911930 @default.
- W4313446518 cites W2009441924 @default.
- W4313446518 cites W2019013597 @default.
- W4313446518 cites W2023613739 @default.
- W4313446518 cites W2023879527 @default.
- W4313446518 cites W2038103483 @default.
- W4313446518 cites W2038538526 @default.
- W4313446518 cites W2043465974 @default.
- W4313446518 cites W2053726603 @default.
- W4313446518 cites W2063334919 @default.
- W4313446518 cites W2077783557 @default.
- W4313446518 cites W2085854546 @default.
- W4313446518 cites W2124088680 @default.
- W4313446518 cites W2279804375 @default.
- W4313446518 cites W2297714457 @default.
- W4313446518 cites W2312693181 @default.
- W4313446518 cites W2327470969 @default.
- W4313446518 cites W2462949473 @default.
- W4313446518 cites W2500146068 @default.
- W4313446518 cites W2530843055 @default.
- W4313446518 cites W2600597431 @default.
- W4313446518 cites W2619215515 @default.
- W4313446518 cites W2624362495 @default.
- W4313446518 cites W2765289012 @default.
- W4313446518 cites W2766729476 @default.
- W4313446518 cites W2767085640 @default.
- W4313446518 cites W2798004138 @default.
- W4313446518 cites W2809373477 @default.
- W4313446518 cites W2896849243 @default.
- W4313446518 cites W2899525914 @default.
- W4313446518 cites W2903385757 @default.
- W4313446518 cites W2911843613 @default.
- W4313446518 cites W2937099783 @default.
- W4313446518 cites W2963151166 @default.
- W4313446518 cites W2970117122 @default.
- W4313446518 cites W2971954520 @default.
- W4313446518 cites W2991441890 @default.
- W4313446518 cites W2998369725 @default.
- W4313446518 cites W2998941884 @default.
- W4313446518 cites W2999568318 @default.
- W4313446518 cites W3000155803 @default.
- W4313446518 cites W3015907080 @default.
- W4313446518 cites W3022581935 @default.
- W4313446518 cites W3023578262 @default.
- W4313446518 cites W3036363536 @default.
- W4313446518 cites W3037280006 @default.
- W4313446518 cites W3042869191 @default.
- W4313446518 cites W3043683253 @default.
- W4313446518 cites W3084251260 @default.
- W4313446518 cites W3093040205 @default.
- W4313446518 cites W3093197078 @default.
- W4313446518 cites W3104020713 @default.
- W4313446518 cites W3119014160 @default.
- W4313446518 cites W3135047136 @default.
- W4313446518 cites W3148143934 @default.
- W4313446518 cites W3158662254 @default.
- W4313446518 cites W3163260644 @default.
- W4313446518 cites W3172223163 @default.
- W4313446518 cites W3177876712 @default.
- W4313446518 cites W4214920114 @default.
- W4313446518 cites W4220916510 @default.
- W4313446518 cites W4237911477 @default.
- W4313446518 cites W4248076276 @default.
- W4313446518 cites W4294671138 @default.
- W4313446518 cites W6021378 @default.
- W4313446518 cites W642240717 @default.
- W4313446518 doi "https://doi.org/10.1021/acscatal.2c05573" @default.
- W4313446518 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36714054" @default.
- W4313446518 hasPublicationYear "2023" @default.
- W4313446518 type Work @default.
- W4313446518 citedByCount "6" @default.
- W4313446518 countsByYear W43134465182023 @default.
- W4313446518 crossrefType "journal-article" @default.
- W4313446518 hasAuthorship W4313446518A5010060889 @default.
- W4313446518 hasAuthorship W4313446518A5056827531 @default.
- W4313446518 hasBestOaLocation W43134465181 @default.
- W4313446518 hasConcept C121332964 @default.
- W4313446518 hasConcept C124681953 @default.
- W4313446518 hasConcept C148898269 @default.
- W4313446518 hasConcept C153914509 @default.
- W4313446518 hasConcept C161790260 @default.
- W4313446518 hasConcept C178790620 @default.
- W4313446518 hasConcept C185592680 @default.
- W4313446518 hasConcept C21951064 @default.