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• W4313448532 startingPage "344" @default.
• W4313448532 abstract "Hexagonal rare-earth ferrites (h-RFeO3) are promising multiferroic materials owing to the spontaneous magnetization, high ferroelectric transition temperature, and fascinating features provided by strong magnetoelectric coupling. However, h-RFeO3 is metastable, and its synthetic methods are limited, particularly when ionic size of R is large. One of useful synthesis methods is epitaxial thin-film growth on single-crystal substrates, because the metastable phase is stabilized by the lattice match between h-RFeO3 and the substrate. Compared to single-crystal substrates, glass substrates are more cost-effective. However, films on glass tend to consist of a thermodynamically stable phase owing to the amorphous nature of glass substrates. Herein, we report that a h-RFeO3 pure phase can be obtained as thin film even on glass substrates. The metastable phase was formed owing to the nonequilibrium synthesis process of pulsed laser deposition. The obtained h-RFeO3 thin films on glass with R = Dy, Er, and Lu exhibited weak ferromagnetism with Néel temperatures of 120–140 K. Furthermore, a clear magnetic phase transition from weak ferromagnetic to antiferromagnetic phase was observed in the h-ErFeO3 films. Additionally, piezoelectric force microscopy measurements exhibited the ferroelectricity of the film at room temperature. These results provide a convenient synthesis method of a pure phase multiferroic h-RFeO3 system." @default.
• W4313448532 created "2023-01-06" @default.
• W4313448532 creator A5041930406 @default.
• W4313448532 creator A5078328036 @default.
• W4313448532 date "2022-12-20" @default.
• W4313448532 modified "2023-09-27" @default.
• W4313448532 title "Hexagonal <i>R</i>FeO₃ (<i>R</i> = Dy, Er, and Lu) Films Grown on Glass Substrates with Both Magnetic and Ferroelectric Orders" @default.
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• W4313448532 doi "https://doi.org/10.1021/acsaelm.2c01356" @default.
• W4313448532 hasPublicationYear "2022" @default.
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