Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313454193> ?p ?o ?g. }
- W4313454193 abstract "Reentrant phenomena in soft matter and biosystems have attracted considerable attention because their properties are closely related to high functionality. Here, we report a combined experimental and computational study on the self-assembly and reentrant behavior of a single-component thermotropic smectic liquid crystal toward the realization of dynamically functional materials. We have designed and synthesized a mesogenic molecule consisting of an alicyclic trans,trans-bicyclohexyl mesogen and a polar cyclic carbonate group connected by a flexible tetra(oxyethylene) spacer. The molecule exhibits an unprecedented sequence of layered smectic phases, in the order: smectic A-smectic B-reentrant smectic A. Electron density profiles and large-scale molecular dynamics simulations indicate that competition between the stacking of bicyclohexyl mesogens and the conformational flexibility of tetra(oxyethylene) chains induces this unusual reentrant behavior. Ion-conductive reentrant liquid-crystalline materials have been developed, which undergo the multistep conductivity changes in response to temperature. The reentrant liquid crystals have potential as new mesogenic materials exhibiting switching functions." @default.
- W4313454193 created "2023-01-06" @default.
- W4313454193 creator A5001317668 @default.
- W4313454193 creator A5005341858 @default.
- W4313454193 creator A5009612150 @default.
- W4313454193 creator A5011805835 @default.
- W4313454193 creator A5014540881 @default.
- W4313454193 creator A5019717508 @default.
- W4313454193 creator A5045603336 @default.
- W4313454193 creator A5055741343 @default.
- W4313454193 creator A5059531454 @default.
- W4313454193 creator A5070315511 @default.
- W4313454193 creator A5072294943 @default.
- W4313454193 date "2023-01-23" @default.
- W4313454193 modified "2023-09-30" @default.
- W4313454193 title "Reentrant 2D Nanostructured Liquid Crystals by Competition between Molecular Packing and Conformation: Potential Design for Multistep Switching of Ionic Conductivity" @default.
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