FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313454741> ?p ?o ?g. }

• W4313454741 endingPage "2900" @default.
• W4313454741 startingPage "2891" @default.
• W4313454741 abstract "The favored production of one product over another is a major challenge in synthetic chemistry, reducing the formation of byproducts and enhancing atom efficacy. The formation of catalytic species that have differing reactivities based on the substrate being converted, has been targeted to selectively control reactions. Here, we report the production of photocatalytic self-assembled amphiphilic polymers, with either hydrophilic or hydrophobic microenvironments at the reactive center. Benzothiadiazole-based photocatalysts were polymerized into either the hydrophilic or the hydrophobic compartment of a diblock copolymer by RAFT polymerization. The difference in the reactivity of each microenvironment was dictated by the physical properties of the substrate. Stark differences in reactivity were observed for polar substrates, where a hydrophilic microenvironment was favored. Conversely, both microenvironments performed similarly for very hydrophobic substrates, showing that reagent partitioning is not the only factor that drives photocatalytic conversion. Furthermore, the use of secondary swelling solvents allowed an additional reagent exchange between the continuous phase and the heterogeneous photocatalyst, resulting in a significant 5-fold increase in conversion for a radical carbon-carbon coupling." @default.
• W4313454741 created "2023-01-06" @default.
• W4313454741 creator A5008122221 @default.
• W4313454741 creator A5034838011 @default.
• W4313454741 creator A5042275051 @default.
• W4313454741 creator A5063724311 @default.
• W4313454741 creator A5066299239 @default.
• W4313454741 date "2023-01-03" @default.
• W4313454741 modified "2023-09-23" @default.
• W4313454741 title "Tunable Photocatalytic Selectivity by Altering the Active Center Microenvironment of an Organic Polymer Photocatalyst" @default.
• W4313454741 cites W1602185611 @default.
• W4313454741 cites W1877554950 @default.
• W4313454741 cites W1928964525 @default.
• W4313454741 cites W1990586799 @default.
• W4313454741 cites W2004179906 @default.
• W4313454741 cites W2005619234 @default.
• W4313454741 cites W2009463057 @default.
• W4313454741 cites W2023491051 @default.
• W4313454741 cites W2044230168 @default.
• W4313454741 cites W2048312836 @default.
• W4313454741 cites W2051822378 @default.
• W4313454741 cites W2062355662 @default.
• W4313454741 cites W2063597962 @default.
• W4313454741 cites W2071801044 @default.
• W4313454741 cites W2077895811 @default.
• W4313454741 cites W2079822650 @default.
• W4313454741 cites W2081889709 @default.
• W4313454741 cites W2083119582 @default.
• W4313454741 cites W2095527210 @default.
• W4313454741 cites W2109209239 @default.
• W4313454741 cites W2160666152 @default.
• W4313454741 cites W2227068583 @default.
• W4313454741 cites W2313242819 @default.
• W4313454741 cites W2314126489 @default.
• W4313454741 cites W2314612558 @default.
• W4313454741 cites W2318715202 @default.
• W4313454741 cites W2322758475 @default.
• W4313454741 cites W2325139112 @default.
• W4313454741 cites W2327774501 @default.
• W4313454741 cites W2465811153 @default.
• W4313454741 cites W2470781570 @default.
• W4313454741 cites W2504159405 @default.
• W4313454741 cites W2504256884 @default.
• W4313454741 cites W2564259981 @default.
• W4313454741 cites W2564918709 @default.
• W4313454741 cites W2571824444 @default.
• W4313454741 cites W2737296529 @default.
• W4313454741 cites W2749508283 @default.
• W4313454741 cites W2783030561 @default.
• W4313454741 cites W2794166887 @default.
• W4313454741 cites W2805778464 @default.
• W4313454741 cites W2884193690 @default.
• W4313454741 cites W2899261262 @default.
• W4313454741 cites W2910820311 @default.
• W4313454741 cites W2921161344 @default.
• W4313454741 cites W2941264395 @default.
• W4313454741 cites W2944786846 @default.
• W4313454741 cites W2972519150 @default.
• W4313454741 cites W2974545220 @default.
• W4313454741 cites W2986852127 @default.
• W4313454741 cites W2987566486 @default.
• W4313454741 cites W2999667083 @default.
• W4313454741 cites W3007756315 @default.
• W4313454741 cites W3009905611 @default.
• W4313454741 cites W3030793002 @default.
• W4313454741 cites W3044608971 @default.
• W4313454741 cites W3093081853 @default.
• W4313454741 cites W3094606157 @default.
• W4313454741 cites W3103685754 @default.
• W4313454741 cites W3109842624 @default.
• W4313454741 cites W3113045859 @default.
• W4313454741 cites W3153329320 @default.
• W4313454741 cites W3163878175 @default.
• W4313454741 cites W3190532610 @default.
• W4313454741 cites W3217125349 @default.
• W4313454741 cites W4200327954 @default.
• W4313454741 cites W4206989193 @default.
• W4313454741 cites W4221125570 @default.
• W4313454741 cites W4235290543 @default.
• W4313454741 cites W4246528915 @default.
• W4313454741 cites W4248515780 @default.
• W4313454741 doi "https://doi.org/10.1021/acsami.2c17607" @default.
• W4313454741 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36594942" @default.
• W4313454741 hasPublicationYear "2023" @default.
• W4313454741 type Work @default.
• W4313454741 citedByCount "2" @default.
• W4313454741 countsByYear W43134547412023 @default.
• W4313454741 crossrefType "journal-article" @default.
• W4313454741 hasAuthorship W4313454741A5008122221 @default.
• W4313454741 hasAuthorship W4313454741A5034838011 @default.
• W4313454741 hasAuthorship W4313454741A5042275051 @default.
• W4313454741 hasAuthorship W4313454741A5063724311 @default.
• W4313454741 hasAuthorship W4313454741A5066299239 @default.
• W4313454741 hasBestOaLocation W43134547411 @default.
• W4313454741 hasConcept C111368507 @default.
• W4313454741 hasConcept C118792377 @default.
• W4313454741 hasConcept C127313418 @default.
• W4313454741 hasConcept C127413603 @default.

• next