Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313463377> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W4313463377 endingPage "44" @default.
- W4313463377 startingPage "35" @default.
- W4313463377 abstract "Fluoroethane is a potential fluid or component of new environmentally friendly working fluids, but its flammability affects its direct application. The oxidative decomposition mechanism of the working fluid is the key to further study its flammability or stability. Therefore, the oxidative decomposition mechanism of fluoroethane was researched by density functional theory. Firstly, seven initial thermal decomposition paths of fluoroethane and four oxidative decomposition paths involving oxygen were obtained, among which the main initial decomposition products were CH2=CH2 and HF, and the free radicals were ·CH3, ·CH2F, H·, HOO·, etc.; Secondly, the main reaction process of six typical active radicals generated by the chain reaction and fluoroethane was also studied, and it was found that the energy barrier of the hydrogen-extraction reaction was lower than that of the fluorine-extraction reaction, and most of the reactions were exothermic reactions; Finally, the subsequent reaction processes of the main radicals ·CH3 and ·CH2F in the decomposition of fluoroethane were analyzed, and more than 20 possible products and their energy changes were obtained. The relevant results have guiding significance for weakening the flammability of fluoroethane, improving its thermal stability and evaluating its oxidative decomposition products from the deep mechanism." @default.
- W4313463377 created "2023-01-06" @default.
- W4313463377 creator A5005080274 @default.
- W4313463377 creator A5005647753 @default.
- W4313463377 creator A5022663437 @default.
- W4313463377 creator A5058380236 @default.
- W4313463377 creator A5083948340 @default.
- W4313463377 date "2023-04-01" @default.
- W4313463377 modified "2023-10-14" @default.
- W4313463377 title "Research on oxidation decomposition mechanism of fluoroethane" @default.
- W4313463377 cites W1411685119 @default.
- W4313463377 cites W1969965315 @default.
- W4313463377 cites W1979975276 @default.
- W4313463377 cites W1998278833 @default.
- W4313463377 cites W2012129602 @default.
- W4313463377 cites W2013741729 @default.
- W4313463377 cites W2014767176 @default.
- W4313463377 cites W2027012147 @default.
- W4313463377 cites W2030976617 @default.
- W4313463377 cites W2032923631 @default.
- W4313463377 cites W2066188787 @default.
- W4313463377 cites W2079458939 @default.
- W4313463377 cites W2150697053 @default.
- W4313463377 cites W2230728100 @default.
- W4313463377 cites W2318923246 @default.
- W4313463377 cites W2511716508 @default.
- W4313463377 cites W2518791074 @default.
- W4313463377 cites W2542267785 @default.
- W4313463377 cites W2594416044 @default.
- W4313463377 cites W2619422055 @default.
- W4313463377 cites W2728481879 @default.
- W4313463377 cites W2761695541 @default.
- W4313463377 cites W2765722564 @default.
- W4313463377 cites W2767027734 @default.
- W4313463377 cites W2908498306 @default.
- W4313463377 cites W2963700883 @default.
- W4313463377 cites W2989867788 @default.
- W4313463377 cites W2992259896 @default.
- W4313463377 cites W3006978563 @default.
- W4313463377 cites W3040457501 @default.
- W4313463377 cites W3094578657 @default.
- W4313463377 cites W3105206763 @default.
- W4313463377 cites W3128367646 @default.
- W4313463377 cites W3133821535 @default.
- W4313463377 cites W3156363784 @default.
- W4313463377 cites W3190029998 @default.
- W4313463377 cites W4224300577 @default.
- W4313463377 cites W4252549146 @default.
- W4313463377 doi "https://doi.org/10.1016/j.ijrefrig.2022.12.030" @default.
- W4313463377 hasPublicationYear "2023" @default.
- W4313463377 type Work @default.
- W4313463377 citedByCount "0" @default.
- W4313463377 crossrefType "journal-article" @default.
- W4313463377 hasAuthorship W4313463377A5005080274 @default.
- W4313463377 hasAuthorship W4313463377A5005647753 @default.
- W4313463377 hasAuthorship W4313463377A5022663437 @default.
- W4313463377 hasAuthorship W4313463377A5058380236 @default.
- W4313463377 hasAuthorship W4313463377A5083948340 @default.
- W4313463377 hasConcept C124681953 @default.
- W4313463377 hasConcept C139066938 @default.
- W4313463377 hasConcept C158550234 @default.
- W4313463377 hasConcept C160434732 @default.
- W4313463377 hasConcept C161790260 @default.
- W4313463377 hasConcept C178790620 @default.
- W4313463377 hasConcept C185592680 @default.
- W4313463377 hasConcept C45119746 @default.
- W4313463377 hasConcept C48333953 @default.
- W4313463377 hasConcept C65024703 @default.
- W4313463377 hasConceptScore W4313463377C124681953 @default.
- W4313463377 hasConceptScore W4313463377C139066938 @default.
- W4313463377 hasConceptScore W4313463377C158550234 @default.
- W4313463377 hasConceptScore W4313463377C160434732 @default.
- W4313463377 hasConceptScore W4313463377C161790260 @default.
- W4313463377 hasConceptScore W4313463377C178790620 @default.
- W4313463377 hasConceptScore W4313463377C185592680 @default.
- W4313463377 hasConceptScore W4313463377C45119746 @default.
- W4313463377 hasConceptScore W4313463377C48333953 @default.
- W4313463377 hasConceptScore W4313463377C65024703 @default.
- W4313463377 hasLocation W43134633771 @default.
- W4313463377 hasOpenAccess W4313463377 @default.
- W4313463377 hasPrimaryLocation W43134633771 @default.
- W4313463377 hasRelatedWork W2029394834 @default.
- W4313463377 hasRelatedWork W2041632431 @default.
- W4313463377 hasRelatedWork W2059582583 @default.
- W4313463377 hasRelatedWork W2325212647 @default.
- W4313463377 hasRelatedWork W2357530221 @default.
- W4313463377 hasRelatedWork W2364068004 @default.
- W4313463377 hasRelatedWork W2385677680 @default.
- W4313463377 hasRelatedWork W2804821159 @default.
- W4313463377 hasRelatedWork W3082689770 @default.
- W4313463377 hasRelatedWork W837831919 @default.
- W4313463377 hasVolume "148" @default.
- W4313463377 isParatext "false" @default.
- W4313463377 isRetracted "false" @default.
- W4313463377 workType "article" @default.