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- W4313478489 abstract "Metal doping plays a momentous role in heightening the electronic conductivity of Sn4P3. This work proposes the facile synthesis of Fe-doped Sn4P3 via a solid-state reaction process. The resulting Fe-doped Sn4P3 is stacked by a great quantity of nanoparticles. As the ionic radius of Fe3+ (64.5 p.m.) is slightly smaller than that of Sn4+ (69 p.m.), Fe3+can easily dope into the structure of Sn4P3. The Sn4P3 anode with 5% Fe doping delivers a larger initial discharge capacity of 1105.1 mAh/g and coloumbic efficiency of 86.2%. After 200 cycles, a high discharge capacity of 972.4 mAh/g is reached, while the discharge capacity of un-doped Sn4P3 anode merely maintains at about 423.3 mAh/g. As an inactive matrix, Fe atoms can disperse among Sn atoms, thus inhibiting the aggregation of Sn atoms during cycling. The results display that Fe doping in Sn4P3 structure is extremely vital to heighten the architecture stability and electrochemical performance. This facile solid-state reaction process can be enlarged to the manufacture of other metal-doped Sn4P3 in the field of lithium-ion batteries." @default.
- W4313478489 created "2023-01-06" @default.
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- W4313478489 date "2023-02-01" @default.
- W4313478489 modified "2023-10-18" @default.
- W4313478489 title "Facile synthesis of Fe-doped Sn4P3 anode materials for high-performance lithium-ion batteries" @default.
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- W4313478489 doi "https://doi.org/10.1016/j.solidstatesciences.2022.107108" @default.
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