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• W4313478813 abstract "The complementariness of biomass residues and plastic waste may be leveraged into fuels and other chemicals via co-pyrolysis in order to decrease our dependence on fossil fuels and increase the circularity of waste streams. The co-pyrolysis of pineapple rind (PR) and low density polyethylene (LDPE) was conducted to characterize its kinetic and interaction mechanisms and products. The co-pyrolysis was best elucidated by three stages where synergistic (facilitative) and antagonistic (inhibitory) effects dominated at below and above 495 ℃, respectively. The activation energy requirement was lower for the co-pyrolysis than the individual PR or LDPE. The lowest co-pyrolysis activation energy (129.17 kJ/mol) occurred with the addition of 50% LDPE. F1, F1, F2, and R2 mechanisms best described the co-pyrolytic kinetics of the blend sample with 50% LDPE at four temperatures. The co-pyrolysis inhibited the production of CO2 and promoted the formation of CH4. The production of acids, aldehydes, and ketones fell significantly during the co-pyrolysis. The variation of these compounds improved the quality of pyrolytic oils. The multi-objective optimization based on the best-fit artificial neural network pointed to the range of 550–800 ℃ and 10 ℃/min for the co-pyrolysis of 50% LDPE and 50% PR as the optimal operational conditions. This study provided new and actionable insights into the optimization of the co-pyrolysis of fruit residues and plastic polymers." @default.
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• W4313478813 date "2023-01-01" @default.
• W4313478813 modified "2023-10-18" @default.
• W4313478813 title "Co-pyrolytic kinetic and interaction mechanisms and products of pineapple rind and low density polyethylene" @default.
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• W4313478813 doi "https://doi.org/10.1016/j.jaap.2022.105850" @default.
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