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- W4313478916 abstract "A trinuclear bis-cyclometalated iridium(III) polypyridyl complex was synthesised and evaluated as a photoredox catalyst for visible light-mediated thiol-ene coupling reactions. Electronic absorption and emission studies revealed that the complex shows a blue-shifted emission spectrum, with a wavelength at 578 nm, relative to the canonical iridium complex, [Ir(ppy)3] (598 nm). The emissions are attributed to the transition from the triplet MLCT excited state (3MLCT) to the ground state. Cyclic voltammetry studies demonstrated that this complex is a promising candidate for photoredox catalysed reactions, with the trinuclear iridium complex increasing the oxidation potential without sacrificing the reduction ability. The iridium(III) complex was evaluated as a photoredox catalyst in the model hydrothiolation coupling reaction and benchmarked against a trinuclear ruthenium congener. Reactions conducted with the trinuclear iridium polypyridyl complex resulted in the highest NMR yields." @default.
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- W4313478916 date "2023-03-01" @default.
- W4313478916 modified "2023-10-18" @default.
- W4313478916 title "Evaluation of a trinuclear heteroleptic bis-cyclometalated iridium(III) complex as a photoredox catalyst for visible light-mediated hydrothiolation reactions" @default.
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- W4313478916 doi "https://doi.org/10.1016/j.inoche.2022.110384" @default.
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