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- W4313479857 abstract "Sulfur poisoning could result in fast deterioration of Pd-based membranes by the formation of metal sulfides and reduction of hydrogen purity. The introduction of an MoO2/TS-1 layer could provide an effective protection of the Pd layer. Therefore, in this paper a synthetic method is presented for preparation of sulfur-resistant MoO2/TS-1 zeolite modified PdCu alloy composite membranes and their application in hydrogen separation under H2S containing steam. According to the stability test results, the MoO2/TS-1 zeolite armored layer obviously prolonged the stability of Pd based membrane. After 50 h stability test with 100 ppm H2S, there were no obvious structural changes and metal sulfide formation detected in the PdCu bulk from SEM images and XRD patterns, indicating that MoO2/TS-1 armor structure was good enough for protecting the PdCu alloy bulk." @default.
- W4313479857 created "2023-01-06" @default.
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- W4313479857 date "2023-05-01" @default.
- W4313479857 modified "2023-10-14" @default.
- W4313479857 title "Sulfur-resistant MoO2/TS-1 zeolite armored PdCu alloy composite membrane for hydrogen separation under H2S containing steam" @default.
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- W4313479857 doi "https://doi.org/10.1016/j.memlet.2023.100037" @default.
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