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- W4313480327 abstract "Converting biomass into valuable aromatics is a desirable way to alleviate global energy crisis but is currently challenged by massive energy consumption. Herein, a H2-free melting-catalysis strategy is proposed for direct converting glucose into aromatics under mild conditions by nano-sized mesoporous ZSM-5. We demonstrate that the melting of glucose promotes the accessibility to catalytic sites and enhances subsequent catalytic processes. The introduction of inter-crystalline mesopores facilitates diffusion of molecules, and the moderate acidity favors the deoxygenation of oxygenated intermediates, both of which promote aromatics formation. Consequently, 10-ZSM-5–80 with abundant inter-crystalline mesopores and optimum acidity achieves a maximum aromatics selectivity of 95.4 area% at 280 °C, of which 70.2% are monocyclic aromatic hydrocarbons. Furthermore, a possible mechanism is proposed based on experimental and online TG-FTIR-MS results. Our findings provide a new pathway for the selective generation of aromatics from glucose, which is expected to advance next-generation biomass utilization." @default.
- W4313480327 created "2023-01-06" @default.
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- W4313480327 date "2023-05-01" @default.
- W4313480327 modified "2023-10-14" @default.
- W4313480327 title "Low temperature upgrading glucose to aromatics via a H2-free melting-catalysis strategy" @default.
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- W4313480327 doi "https://doi.org/10.1016/j.apcatb.2022.122226" @default.
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