Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313480515> ?p ?o ?g. }
- W4313480515 endingPage "12320" @default.
- W4313480515 startingPage "12309" @default.
- W4313480515 abstract "Two-dimensional Mo2C (2D-Mo2C) is reported for the first time as an effective promoter of a Pt/Al2O3 catalyst for both the hydrogenation and dehydrogenation of the liquid organic hydrogen carrier (LOHC) pair, dibenzyltoluene (DBT) and perhydro-dibenzyltoluene (H18-DBT), respectively. Addition of 6.2 wt% 2D-Mo2C to a Pt/Al2O3 catalyst resulted in a significant increase in both the degree of hydrogenation and dehydrogenation compared to the unpromoted catalyst. An analysis of the initial (120 min) perhydro-DBT dehydrogenation kinetics in the temperature range of 270–330 °C, resulted in a reduction in apparent activation energy from 119.5 ± 3.8 kJ/mol for the Pt/Al2O3 catalyst to 110.4 ± 5.6 kJ/mol for the 6.2 wt% 2D-Mo2C/Pt/Al2O3 catalyst. The 6.2 wt% 2D-Mo2C/Pt/Al2O3 catalyst was also more stable than the unpromoted catalyst over several consecutive cycles of hydrogenation and dehydrogenation. Catalyst characterization showed that addition of 2D-Mo2C resulted in an increase in particle size and electron density of the Pt, which enhanced both the hydrogenation and dehydrogenation reactions, despite the fact that the 2D-Mo2C alone was inactive for both reactions." @default.
- W4313480515 created "2023-01-06" @default.
- W4313480515 creator A5003355274 @default.
- W4313480515 creator A5012923773 @default.
- W4313480515 creator A5042635829 @default.
- W4313480515 date "2023-04-01" @default.
- W4313480515 modified "2023-10-01" @default.
- W4313480515 title "Two-dimensional Mo2C: An efficient promoter for hydrogen storage and release from a liquid organic hydrogen carrier" @default.
- W4313480515 cites W1423283317 @default.
- W4313480515 cites W1968553627 @default.
- W4313480515 cites W1973434078 @default.
- W4313480515 cites W2023340293 @default.
- W4313480515 cites W2037341385 @default.
- W4313480515 cites W2099668314 @default.
- W4313480515 cites W2110041084 @default.
- W4313480515 cites W2130789799 @default.
- W4313480515 cites W2276720620 @default.
- W4313480515 cites W2337647621 @default.
- W4313480515 cites W2340744176 @default.
- W4313480515 cites W2406788928 @default.
- W4313480515 cites W2560894534 @default.
- W4313480515 cites W2597054437 @default.
- W4313480515 cites W2626611253 @default.
- W4313480515 cites W2762921792 @default.
- W4313480515 cites W2802771054 @default.
- W4313480515 cites W2897260961 @default.
- W4313480515 cites W2902972860 @default.
- W4313480515 cites W2912216865 @default.
- W4313480515 cites W2937269717 @default.
- W4313480515 cites W2946281699 @default.
- W4313480515 cites W2963115827 @default.
- W4313480515 cites W3001094024 @default.
- W4313480515 cites W3014733320 @default.
- W4313480515 cites W3047475533 @default.
- W4313480515 cites W3080095628 @default.
- W4313480515 cites W3087182797 @default.
- W4313480515 cites W3091210043 @default.
- W4313480515 cites W3091872318 @default.
- W4313480515 cites W3098404609 @default.
- W4313480515 cites W3128312577 @default.
- W4313480515 cites W3138151949 @default.
- W4313480515 cites W3159169984 @default.
- W4313480515 cites W3168816197 @default.
- W4313480515 cites W3171800681 @default.
- W4313480515 cites W3188575239 @default.
- W4313480515 cites W3217486786 @default.
- W4313480515 cites W4200513433 @default.
- W4313480515 doi "https://doi.org/10.1016/j.ijhydene.2022.11.291" @default.
- W4313480515 hasPublicationYear "2023" @default.
- W4313480515 type Work @default.
- W4313480515 citedByCount "3" @default.
- W4313480515 countsByYear W43134805152023 @default.
- W4313480515 crossrefType "journal-article" @default.
- W4313480515 hasAuthorship W4313480515A5003355274 @default.
- W4313480515 hasAuthorship W4313480515A5012923773 @default.
- W4313480515 hasAuthorship W4313480515A5042635829 @default.
- W4313480515 hasConcept C119889771 @default.
- W4313480515 hasConcept C121332964 @default.
- W4313480515 hasConcept C127413603 @default.
- W4313480515 hasConcept C148898269 @default.
- W4313480515 hasConcept C161790260 @default.
- W4313480515 hasConcept C178790620 @default.
- W4313480515 hasConcept C179104552 @default.
- W4313480515 hasConcept C185592680 @default.
- W4313480515 hasConcept C42360764 @default.
- W4313480515 hasConcept C512968161 @default.
- W4313480515 hasConcept C62520636 @default.
- W4313480515 hasConcept C68044625 @default.
- W4313480515 hasConcept C95121573 @default.
- W4313480515 hasConceptScore W4313480515C119889771 @default.
- W4313480515 hasConceptScore W4313480515C121332964 @default.
- W4313480515 hasConceptScore W4313480515C127413603 @default.
- W4313480515 hasConceptScore W4313480515C148898269 @default.
- W4313480515 hasConceptScore W4313480515C161790260 @default.
- W4313480515 hasConceptScore W4313480515C178790620 @default.
- W4313480515 hasConceptScore W4313480515C179104552 @default.
- W4313480515 hasConceptScore W4313480515C185592680 @default.
- W4313480515 hasConceptScore W4313480515C42360764 @default.
- W4313480515 hasConceptScore W4313480515C512968161 @default.
- W4313480515 hasConceptScore W4313480515C62520636 @default.
- W4313480515 hasConceptScore W4313480515C68044625 @default.
- W4313480515 hasConceptScore W4313480515C95121573 @default.
- W4313480515 hasFunder F4320334593 @default.
- W4313480515 hasIssue "33" @default.
- W4313480515 hasLocation W43134805151 @default.
- W4313480515 hasOpenAccess W4313480515 @default.
- W4313480515 hasPrimaryLocation W43134805151 @default.
- W4313480515 hasRelatedWork W1570196808 @default.
- W4313480515 hasRelatedWork W2048736733 @default.
- W4313480515 hasRelatedWork W2063890476 @default.
- W4313480515 hasRelatedWork W2327808458 @default.
- W4313480515 hasRelatedWork W2342612597 @default.
- W4313480515 hasRelatedWork W2755804411 @default.
- W4313480515 hasRelatedWork W3011967486 @default.
- W4313480515 hasRelatedWork W4280548561 @default.
- W4313480515 hasRelatedWork W4309721810 @default.
- W4313480515 hasRelatedWork W4313480515 @default.
- W4313480515 hasVolume "48" @default.