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• W4313481521 endingPage "14119" @default.
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• W4313481521 abstract "Dual-band electrochromic smart window (ESW), which can independently modulate the visible and NIR transmittance, was significant to the modern building energy consumption. However, the key dual-band electrochromic composite required deliberate architecting. Herein, a facile route of controlling the crystallinity of oxygen-deficient tungsten oxide (WO3-x) on SnO2 nanoflake arrays (SnO2) was designed for advanced dual-band ESW. The crystalline/amorphous WO3-x on SnO2 complemented each other, and possessed clear responsibilities. Firstly, the middle monoclinic WO3-x (m-WO3-x) was mainly responsible for the “cool” mode by the LSPR modulation, and the “dark” mode was simultaneously modulated by the small polaron absorption of the top amorphous WO3-x (a-WO3-x) and the phase change of the middle m-WO3-x. Secondly, the top a-WO3-x permitted the infiltration of electrolyte with the middle m-WO3-x and improved the ion-insertion/extraction rate. Thirdly, the bottom SnO2 was beneficial to upholding the crystalline/amorphous WO3-x and accelerating the diffusion rate of Li+. As expected, the assembled ESW with the designed WO3-x/SnO2 exhibited three optical modes (“bright, cool, and dark”) in the visible and NIR light region, and revealed favorable electrochromic performance." @default.
• W4313481521 created "2023-01-06" @default.
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• W4313481521 date "2023-05-01" @default.
• W4313481521 modified "2023-10-16" @default.
• W4313481521 title "Controlling crystallinity of oxygen-deficient tungsten oxide on SnO2 nanoflake arrays for advanced dual-band electrochromic smart window" @default.
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• W4313481521 doi "https://doi.org/10.1016/j.ceramint.2022.12.292" @default.
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