Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313488302> ?p ?o ?g. }
Showing items 1 to 94 of
94
with 100 items per page.
- W4313488302 abstract "Uranyl peroxide nanoclusters are an evolving family of materials with potential applications throughout the nuclear fuel cycle. While several studies have investigated their interactions with alkali and alkaline earth metals, no studies have probed their interactions with the actinide elements. This work describes a system containing U60Ox30, [((UO2)(O2))60(C2O4)30]60−, and neptunium(V) as a function of neptunium concentration. Ultra-small and small angle X-ray scattering were used to observe these interactions in the aqueous phase, and X-ray diffraction was used to observe solid products. The results show that neptunium induces aggregation of U60Ox30 when the neptunium concentration is≤10 mM, whereas (NpO2)2C2O4 ⋅ 6H2O(cr) and studtite ultimately form at 15–25 mM neptunium. The latter result suggests that neptunium coordinates with the bridging oxalate ligands in U60Ox30, leaving metastable uranyl peroxide species in solution. This is an important finding given the potential application of uranyl peroxide nanoclusters in the recycling of used nuclear fuel." @default.
- W4313488302 created "2023-01-06" @default.
- W4313488302 creator A5043702852 @default.
- W4313488302 creator A5074151270 @default.
- W4313488302 creator A5077896219 @default.
- W4313488302 date "2023-03-01" @default.
- W4313488302 modified "2023-09-27" @default.
- W4313488302 title "Crystallization of a Neptunyl Oxalate Hydrate from Solutions Containing Np<sup>V</sup> and the Uranyl Peroxide Nanocluster U<sub>60</sub>Ox<sub>30</sub>" @default.
- W4313488302 cites W1970177602 @default.
- W4313488302 cites W1975834815 @default.
- W4313488302 cites W1984282052 @default.
- W4313488302 cites W1989275496 @default.
- W4313488302 cites W1998014580 @default.
- W4313488302 cites W2003667498 @default.
- W4313488302 cites W2019578380 @default.
- W4313488302 cites W2020658690 @default.
- W4313488302 cites W2021718273 @default.
- W4313488302 cites W2035235878 @default.
- W4313488302 cites W2035755460 @default.
- W4313488302 cites W2064286734 @default.
- W4313488302 cites W2105418804 @default.
- W4313488302 cites W2138514559 @default.
- W4313488302 cites W2218578352 @default.
- W4313488302 cites W2219221533 @default.
- W4313488302 cites W2321746052 @default.
- W4313488302 cites W2332692943 @default.
- W4313488302 cites W2337629365 @default.
- W4313488302 cites W2557918631 @default.
- W4313488302 cites W2789453133 @default.
- W4313488302 cites W2805756965 @default.
- W4313488302 cites W2920994912 @default.
- W4313488302 cites W2942511578 @default.
- W4313488302 cites W3001406508 @default.
- W4313488302 cites W3023287218 @default.
- W4313488302 cites W4214715245 @default.
- W4313488302 cites W4242382745 @default.
- W4313488302 cites W4255364966 @default.
- W4313488302 doi "https://doi.org/10.1002/chem.202203814" @default.
- W4313488302 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36598408" @default.
- W4313488302 hasPublicationYear "2023" @default.
- W4313488302 type Work @default.
- W4313488302 citedByCount "0" @default.
- W4313488302 crossrefType "journal-article" @default.
- W4313488302 hasAuthorship W4313488302A5043702852 @default.
- W4313488302 hasAuthorship W4313488302A5074151270 @default.
- W4313488302 hasAuthorship W4313488302A5077896219 @default.
- W4313488302 hasConcept C135788738 @default.
- W4313488302 hasConcept C13965031 @default.
- W4313488302 hasConcept C145148216 @default.
- W4313488302 hasConcept C147789679 @default.
- W4313488302 hasConcept C178790620 @default.
- W4313488302 hasConcept C179104552 @default.
- W4313488302 hasConcept C184651966 @default.
- W4313488302 hasConcept C185592680 @default.
- W4313488302 hasConcept C2776351790 @default.
- W4313488302 hasConcept C2778402822 @default.
- W4313488302 hasConcept C2778468930 @default.
- W4313488302 hasConcept C516372188 @default.
- W4313488302 hasConcept C552554468 @default.
- W4313488302 hasConceptScore W4313488302C135788738 @default.
- W4313488302 hasConceptScore W4313488302C13965031 @default.
- W4313488302 hasConceptScore W4313488302C145148216 @default.
- W4313488302 hasConceptScore W4313488302C147789679 @default.
- W4313488302 hasConceptScore W4313488302C178790620 @default.
- W4313488302 hasConceptScore W4313488302C179104552 @default.
- W4313488302 hasConceptScore W4313488302C184651966 @default.
- W4313488302 hasConceptScore W4313488302C185592680 @default.
- W4313488302 hasConceptScore W4313488302C2776351790 @default.
- W4313488302 hasConceptScore W4313488302C2778402822 @default.
- W4313488302 hasConceptScore W4313488302C2778468930 @default.
- W4313488302 hasConceptScore W4313488302C516372188 @default.
- W4313488302 hasConceptScore W4313488302C552554468 @default.
- W4313488302 hasFunder F4320337480 @default.
- W4313488302 hasIssue "19" @default.
- W4313488302 hasLocation W43134883021 @default.
- W4313488302 hasLocation W43134883022 @default.
- W4313488302 hasLocation W43134883023 @default.
- W4313488302 hasLocation W43134883024 @default.
- W4313488302 hasOpenAccess W4313488302 @default.
- W4313488302 hasPrimaryLocation W43134883021 @default.
- W4313488302 hasRelatedWork W1541192802 @default.
- W4313488302 hasRelatedWork W1584327482 @default.
- W4313488302 hasRelatedWork W2027358984 @default.
- W4313488302 hasRelatedWork W2087358317 @default.
- W4313488302 hasRelatedWork W2095983442 @default.
- W4313488302 hasRelatedWork W2527161233 @default.
- W4313488302 hasRelatedWork W4211222447 @default.
- W4313488302 hasRelatedWork W4214702428 @default.
- W4313488302 hasRelatedWork W4287182013 @default.
- W4313488302 hasRelatedWork W4313488302 @default.
- W4313488302 hasVolume "29" @default.
- W4313488302 isParatext "false" @default.
- W4313488302 isRetracted "false" @default.
- W4313488302 workType "article" @default.