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- W4313491010 abstract "Metal-porphyrins or metal-phthalocyanines-based organic frameworks (POFs), an emerging family of metal-N-C materials, have attracted widespread interest for application in electrocatalysis due to their unique metal-N4 coordination structure, high conjugated π-electron system, tunable components, and chemical stability. The key challenges of POFs as high-performance electrocatalysts are the need for rational design for porphyrins/phthalocyanines building blocks and an in-depth understanding of structure-activity relationships. Herein, the synthesis methods, the catalytic activity modulation principles, and the electrocatalytic behaviors of 2D/3D POFs are summarized. Notably, detailed pathways are given for modulating the intrinsic activity of the M-N4 site by the microenvironments, including central metal ions, substituent groups, and heteroatom dopants. Meanwhile, the topology tuning and hybrid system, which affect the conjugation network or conductivity of POFs, are also considered. Furthermore, the representative electrocatalytic applications of structured POFs in efficient and environmental-friendly energy conversion areas, such as carbon dioxide reduction reaction, oxygen reduction reaction, and water splitting are briefly discussed. Overall, this comprehensive review focusing on the frontier will provide multidisciplinary and multi-perspective guidance for the subsequent experimental and theoretical progress of POFs and reveal their key challenges and application prospects in future electrocatalytic energy conversion systems." @default.
- W4313491010 created "2023-01-06" @default.
- W4313491010 creator A5013162667 @default.
- W4313491010 creator A5013295106 @default.
- W4313491010 creator A5014942240 @default.
- W4313491010 creator A5021167946 @default.
- W4313491010 creator A5025797156 @default.
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- W4313491010 creator A5033375534 @default.
- W4313491010 creator A5061084605 @default.
- W4313491010 creator A5064093919 @default.
- W4313491010 creator A5079790858 @default.
- W4313491010 date "2023-01-04" @default.
- W4313491010 modified "2023-10-17" @default.
- W4313491010 title "Electrocatalytic Porphyrin/Phthalocyanine‐Based Organic Frameworks: Building Blocks, Coordination Microenvironments, Structure‐Performance Relationships" @default.
- W4313491010 cites W1967547501 @default.
- W4313491010 cites W1967553820 @default.
- W4313491010 cites W1967812076 @default.
- W4313491010 cites W1971113415 @default.
- W4313491010 cites W1973891115 @default.
- W4313491010 cites W1977093691 @default.
- W4313491010 cites W1978526482 @default.
- W4313491010 cites W1985316960 @default.
- W4313491010 cites W1991466943 @default.
- W4313491010 cites W1992464644 @default.
- W4313491010 cites W1996766403 @default.
- W4313491010 cites W1998298257 @default.
- W4313491010 cites W2004983112 @default.
- W4313491010 cites W2006335338 @default.
- W4313491010 cites W2007471212 @default.
- W4313491010 cites W2009901571 @default.
- W4313491010 cites W2011999890 @default.
- W4313491010 cites W2015124676 @default.
- W4313491010 cites W2022781082 @default.
- W4313491010 cites W2025283862 @default.
- W4313491010 cites W2025286111 @default.
- W4313491010 cites W2027687198 @default.
- W4313491010 cites W2030938880 @default.
- W4313491010 cites W2031302556 @default.
- W4313491010 cites W2035784231 @default.
- W4313491010 cites W2042362062 @default.
- W4313491010 cites W2044830011 @default.
- W4313491010 cites W2044944060 @default.
- W4313491010 cites W2049145344 @default.
- W4313491010 cites W2060696625 @default.
- W4313491010 cites W2063496385 @default.
- W4313491010 cites W2064375934 @default.
- W4313491010 cites W2072701796 @default.
- W4313491010 cites W2088010263 @default.
- W4313491010 cites W2092903091 @default.
- W4313491010 cites W2094559512 @default.
- W4313491010 cites W2105333668 @default.
- W4313491010 cites W2105840458 @default.
- W4313491010 cites W2109772367 @default.
- W4313491010 cites W2125635268 @default.
- W4313491010 cites W2135572322 @default.
- W4313491010 cites W2137818170 @default.
- W4313491010 cites W2140592358 @default.
- W4313491010 cites W2154310752 @default.
- W4313491010 cites W2157782216 @default.
- W4313491010 cites W2169162869 @default.
- W4313491010 cites W2201513017 @default.
- W4313491010 cites W2238210223 @default.
- W4313491010 cites W2239476714 @default.
- W4313491010 cites W2272252865 @default.
- W4313491010 cites W2279490582 @default.
- W4313491010 cites W2283564633 @default.
- W4313491010 cites W2291524002 @default.
- W4313491010 cites W2313035794 @default.
- W4313491010 cites W2327756207 @default.
- W4313491010 cites W2330915705 @default.
- W4313491010 cites W2334842819 @default.
- W4313491010 cites W2340814919 @default.
- W4313491010 cites W2404600454 @default.
- W4313491010 cites W2420611669 @default.
- W4313491010 cites W2480122429 @default.
- W4313491010 cites W2492022654 @default.
- W4313491010 cites W2523161280 @default.
- W4313491010 cites W2524524179 @default.
- W4313491010 cites W2532884284 @default.
- W4313491010 cites W2533682189 @default.
- W4313491010 cites W2559757410 @default.
- W4313491010 cites W2559894501 @default.
- W4313491010 cites W2567277011 @default.
- W4313491010 cites W2591409535 @default.
- W4313491010 cites W2618590689 @default.
- W4313491010 cites W2622519202 @default.
- W4313491010 cites W2626633488 @default.
- W4313491010 cites W2733683283 @default.
- W4313491010 cites W2756361408 @default.
- W4313491010 cites W2770249372 @default.
- W4313491010 cites W2771797445 @default.
- W4313491010 cites W2777278951 @default.
- W4313491010 cites W2801683685 @default.
- W4313491010 cites W2841360875 @default.
- W4313491010 cites W2886608297 @default.
- W4313491010 cites W2893262219 @default.
- W4313491010 cites W2897574808 @default.
- W4313491010 cites W2898856659 @default.
- W4313491010 cites W2899664014 @default.