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- W4313528057 abstract "A copper-catalyzed, redox-neutral cascade difluoroalkylation/5-endo annulation/β-fluorine cleavage of ynones is developed, providing a direct and stereoselective method to access synthetically important α-monofluoroalkenyl cyclopentanones. Mechanistic studies suggest an unprecedented CuII-assisted β-fluorine fragmentation, which may be valuable for the challenging but important C-F bond activation. Moreover, the in situ generated difluorocarbene was found to serve as an effective reductant for the regeneration of copper(I) catalyst, thus avoiding the addition of external reductants." @default.
- W4313528057 created "2023-01-06" @default.
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- W4313528057 date "2023-01-01" @default.
- W4313528057 modified "2023-10-16" @default.
- W4313528057 title "Cu-catalyzed cascade difluoroalkylation/5-<i>endo</i> cyclization/β-fluorine cleavage of ynones" @default.
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- W4313528057 doi "https://doi.org/10.1039/d2cc06068j" @default.
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