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- W4313532451 abstract "Abstract A click chemistry‐based protocol has been utilized for the synthesis of a series of twelve novel tert ‐butyldiphenylsilylated N 1 ‐(coumarin‐4′′′‐yl)‐ C 4 ‐(2′,3′‐di‐deoxyuridin‐3′‐yl)‐oxymethyl‐1,2,3‐triazoles and N 1 ‐(coumarin‐4′′′‐yl)‐ C 4 ‐(3′‐deoxythymin‐3′‐yl)‐oxymethyl‐1,2,3‐triazoles by utilising Cu(I)‐catalyzed azide‐alkyne cycloaddition reaction of 4‐azidocoumarins and 3′‐ O ‐(prop‐1‐yn‐3‐yl)‐5′‐ O ‐( tert ‐butyldiphenylsilyl)‐2′,3′‐dideoxyuridin or 3′‐ O ‐(prop‐1‐yn‐3‐yl)‐5′‐ O ‐( tert ‐butyldiphenylsilyl)‐3′‐deoxythymidin in 70–82 % and 68–82 % yields, respectively. The deprotection of resulted silylated uridine and thymidine conjugate with TBAF afforded title compounds in 81–91 % yield. The photophysical studies have been carried out on the synthesized coumarin‐triazolylmethyl nucleoside conjugates which revealed a very high Stokes shift value ranging from 82–215 nm." @default.
- W4313532451 created "2023-01-06" @default.
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- W4313532451 date "2023-01-03" @default.
- W4313532451 modified "2023-10-12" @default.
- W4313532451 title "Synthesis and Photophysical Studies on <i>N</i><sup>1</sup>‐(Coumarin‐4′′′‐yl)‐<i>C</i><sup>4</sup>‐(2′,3′‐dideoxyuridin‐3′‐yl/3′‐deoxythymidin‐3′‐yl)‐oxymethyl‐1,2,3‐triazoles" @default.
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- W4313532451 doi "https://doi.org/10.1002/slct.202203412" @default.
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