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• W4313537266 endingPage "125801" @default.
• W4313537266 startingPage "125801" @default.
• W4313537266 abstract "Abstract Here we report the evidence of an additional magnetic ordering and frequency dispersive magneto-dielectric (MD) permittivity besides multiferroic behavior in Te 4+ ( S = 0) doped FeVO 4 . Two antiferromagnetic transitions similar to FeVO 4 at ∼21.86 K (T <?CDATA $_{N1}$?> <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML overflow=scroll> <mml:msub> <mml:mi> </mml:mi> <mml:mrow> <mml:mi>N</mml:mi> <mml:mn>1</mml:mn> </mml:mrow> </mml:msub> </mml:math> ) and 16.03 K (T <?CDATA $_{N2}$?> <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML overflow=scroll> <mml:msub> <mml:mi> </mml:mi> <mml:mrow> <mml:mi>N</mml:mi> <mml:mn>2</mml:mn> </mml:mrow> </mml:msub> </mml:math> ) were observed in all samples. An additional novel defect clusters based magnetic ordering at relatively higher temperature (T <?CDATA $_{AMO}$?> <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML overflow=scroll> <mml:msub> <mml:mi /> <mml:mrow> <mml:mi>A</mml:mi> <mml:mi>M</mml:mi> <mml:mi>O</mml:mi> </mml:mrow> </mml:msub> </mml:math> ) ∼ 203 K is also observed from the magnetization. Evaluated magnetic moments show systematic decrease and the magnetic frustration factors show an increase with the increasing of Te 4+ ( S = 0) content. MD studies show stable ferroelectric ordering at spiral magnetic transition (T <?CDATA $_{N2}$?> <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML overflow=scroll> <mml:msub> <mml:mi /> <mml:mrow> <mml:mi>N</mml:mi> <mml:mn>2</mml:mn> </mml:mrow> </mml:msub> </mml:math> ) and the multiferroic order persists to the largest doping of Te ( x = 0.10). The MD studies also reveal a magneto-capacitive (MC) behavior at T <?CDATA $_{AMO}$?> <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML overflow=scroll> <mml:msub> <mml:mi /> <mml:mrow> <mml:mi>A</mml:mi> <mml:mi>M</mml:mi> <mml:mi>O</mml:mi> </mml:mrow> </mml:msub> </mml:math> (∼203 K) with a high dielectric constant and loss, and the possible reason for the magnetic ordering and MC behavior is ascribed to short range magnetic clustering arising out of defect based mechanisms. Mössbauer spectroscopic studies confirm local structural correlation with magnetic and ferroelectric ordering." @default.
• W4313537266 created "2023-01-06" @default.
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• W4313537266 date "2023-01-23" @default.
• W4313537266 modified "2023-10-03" @default.
• W4313537266 title "An additional simultaneous magnetic ordering and magneto-capacitive behavior with dielectric relaxation besides multiferroicity in Fe 1−x Te_xVO₄" @default.
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• W4313537266 doi "https://doi.org/10.1088/1361-648x/acb0a4" @default.
• W4313537266 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36603224" @default.
• W4313537266 hasPublicationYear "2023" @default.
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