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- W4313555005 endingPage "431" @default.
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- W4313555005 abstract "Geminal alkenes bearing an aryl and an allenyl group contain the motif of [3]dendralenes. The central alkene double bond in these cross-conjugated polyenes can be reacted with a silylium ion, thereby initiating a Nazarov cyclization. The cationic intermediate emerging from the electrocyclic ring closure is captured by hydride in the presence of excess hydrosilane. The resulting benzannulated methylenecyclopentene derivatives bearing a silylalkyl group then engage in silylium-ion regeneration followed by an unusual endo-selective intramolecular hydrosilylation. This cascade eventually leads to the formation of a silicon-containing bicyclo[3.2.1]octane skeleton." @default.
- W4313555005 created "2023-01-06" @default.
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- W4313555005 date "2023-01-05" @default.
- W4313555005 modified "2023-10-02" @default.
- W4313555005 title "The [3]Dendralene Motif as an Entry into Nazarov Cyclizations by Silylium-Ion Initiation" @default.
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- W4313555005 doi "https://doi.org/10.1021/acs.orglett.2c04166" @default.
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