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- W4313594534 abstract "Polyoxymethylene dimethyl ethers (PODEn) are promising diesel additives that can reduce the exhaust emission remarkably. Although the thermodynamic model has been proposed for the homogenous synthesis of PODEn, the thermodynamics of heterogeneous synthesis of PODEn from paraformaldehyde and dimethoxymethane is still a challenge because of the complicated characteristics of paraformaldehyde. In this work, a thermodynamic model containing solid paraformaldehyde and liquid dimethoxymethane, methanol and water was established. Experimental validation showed that this model was applicable in a wide range of reaction temperature and feeding composition. This thermodynamic model was then used to study the influence of the reaction temperature, feeding ratio, and addition of water/methanol on the equilibrium conversion. The different starting compositions from heterogeneous and homogenous reactants for the synthesis of PODEn were compared based on thermodynamic analysis, showing that using paraformaldehyde and dimethoxymethane as feedstock gave the highest CH2O conversion and PODE3-5 yield." @default.
- W4313594534 created "2023-01-06" @default.
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- W4313594534 date "2023-04-01" @default.
- W4313594534 modified "2023-09-30" @default.
- W4313594534 title "Thermodynamics of the heterogeneous synthesis of polyoxymethylene dimethyl ethers from paraformaldehyde and dimethoxymethane in presence of methanol and water" @default.
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- W4313594534 doi "https://doi.org/10.1016/j.ces.2022.118424" @default.
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