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- W4313621214 endingPage "1273" @default.
- W4313621214 startingPage "1258" @default.
- W4313621214 abstract "An examination of several catalytic reactions among the group 15 elements is presented. The connections between the chemistry of the pnictogens can sometimes be challenging, but aspects of metal-pnictogen reactivity are the key. The connecting reactivity comes from metal-catalyzed transformations such as dehydrocoupling and hydrofunctionalization. Pivotal mechanistic insights from E-N heterodehydrocoupling have informed the development of highly active catalysts for these reactions. Metal-amido nucleophilicity is often at the core of this reactivity, which diverges from phosphine and arsine dehydrocoupling. Nucleophilicity connects to the earliest understanding of hydrophosphination catalysis, but more recent catalysts are leveraging enhanced insertion activity through photolysis. This photocatalysis extends to hydroarsination, which may also have more metal-arsenido nucleophilicity than anticipated. However, metal-catalyzed arsinidene chemistry foreshadowed related phosphinidene chemistry by years. This examination shows the potential for greater influence of individual discoveries and understanding to leverage new advances between these elements, and it also suggests that the chemistry of heavier elements may have more influence on what is possible with lighter elements." @default.
- W4313621214 created "2023-01-07" @default.
- W4313621214 creator A5020424303 @default.
- W4313621214 creator A5023422981 @default.
- W4313621214 creator A5081073331 @default.
- W4313621214 creator A5081285724 @default.
- W4313621214 creator A5082008611 @default.
- W4313621214 creator A5073000342 @default.
- W4313621214 date "2023-01-01" @default.
- W4313621214 modified "2023-09-26" @default.
- W4313621214 title "Recent advances in catalytic pnictogen bond forming reactions <i>via</i> dehydrocoupling and hydrofunctionalization" @default.
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