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- W4313640770 abstract "Liquid injection field desorption ionization (LIFDI) proves the extraordinary softness of the ionization process combined with a convenient sample supply under the exclusion of moisture and air. LIFDI-mass spectrometry (MS) is used for organometallic and other seriously air-sensitive compounds forming intact ions without substantial fragmentation. Unprecedented molecular radical anions M-• are presented along with well-known intact M+• radical cations. Furthermore closed shell cations [C]+ and adduct ions like [M + H]+ or [M + Alkali]+ are gently transferred from the solid emitter surface into the gas phase. Anions [A]- or [M - H]- are accessible by LIFDI-MS at medium field strengths. Ion pairs [C]+[A]- are separately detected by positive and negative mode LIFDI-MS, respectively. Here we give an overview of the different ion types accessible by LIFDI-MS. For the first time the field ionization/desorption of solar cell electron acceptor compounds is shown to deliver M-• and M2-• radical ions." @default.
- W4313640770 created "2023-01-07" @default.
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- W4313640770 date "2023-01-05" @default.
- W4313640770 modified "2023-09-30" @default.
- W4313640770 title "Unprecedented intact radical anions, closed shell anions, cluster ions, and traditional cations and radical cations by LIFDI–MS" @default.
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- W4313640770 doi "https://doi.org/10.1177/14690667221146079" @default.
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