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- W4313643057 abstract "Abstract A more sustainable and efficient protocol for the photocatalytic α‐amino arylation promoted by fac ‐Ir(ppy) 3 was developed. Three noteworthy results were achieved: i) the replacement of toxic medium DMA with the greener solvents NBP and NHP, and the concurrent improvement of the process efficiency by lowering both the amine and the base amount; ii) the development of a recycling protocol for both the sustainable solvent NHP and the commercially available costly photocatalyst fac ‐Ir(ppy) 3 , achieving environmental and economic benefits. This approach to the photocatalyst recovery avoids very demanding catalyst structural modifications; iii) the protocol in green solvents proved to be scalable up to 10 mmol of limiting reagent, maintaining excellent performance also lowering the photocatalyst loading down to 0.05 mol%. This is the first example of photocatalytic α‐arylation of amines promoted by such a low amount of catalyst. Lastly, the versatility of this approach was demonstrated by extending the use of the green solvent NBP to another photoredox process. magnified image" @default.
- W4313643057 created "2023-01-07" @default.
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- W4313643057 date "2023-01-17" @default.
- W4313643057 modified "2023-09-30" @default.
- W4313643057 title "Towards a More Sustainable Photocatalyzed α‐Arylation of Amines: Green Solvents, Catalyst Recycling and Low Loading" @default.
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- W4313643057 cites W2053626112 @default.
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- W4313643057 doi "https://doi.org/10.1002/adsc.202201123" @default.
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