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- W4313647320 endingPage "110393" @default.
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- W4313647320 abstract "In this work we have synthesized and characterized a new coordination compound [HgL(ClO4)2EtOH] (1), fabricated from a mixture of Hg(NO3)2 and NaClO4 with 1,2-diphenyl-1,2-bis((phenyl-(pyridin-2-yl)methylene)hydrazono)ethane (L). Single-crystal X-ray crystallography revealed the formation of a mononuclear heteroleptic discrete structure with one molecule [HgL(ClO4)2EtOH] in the asymmetric unit. The ligand L adopts a helical twist conformation. The Hg(II) cation is coordinated by four nitrogen atoms from L and by three oxygen atoms from two monocoordinated ClO4– anions and one ethanol molecule. The crystal structure of 1 is stabilized by the intermolecular O–H⋯O hydrogen bonds, and Cl–O⋯πPh and C–H⋯πPh interactions, yielding a supramolecular 3D framework. Moreover, the long Hg–N/O bonds have been analyzed in terms of coordination, semicoordination or spodium bonds using QTAIM and NCIplot index computational tools." @default.
- W4313647320 created "2023-01-07" @default.
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- W4313647320 date "2023-03-01" @default.
- W4313647320 modified "2023-10-03" @default.
- W4313647320 title "Helical coordination complex of Hg(ClO4)2 with bulky hydrazone derivative: A Möbius-like discrete metal chelate" @default.
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- W4313647320 doi "https://doi.org/10.1016/j.inoche.2023.110393" @default.
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