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- W4313649933 abstract "Constructions of heterocyclics by incorporation of CO2 into N-, O- and S-nucleophiles represent advance of synthetic methodology by using CO2 as a C1 feedstock. Herein, we reported crown ether (e.g. 18-crown-6)-catalyzed reductive functionalization of CO2 to various N-containing benzoheterocyclics and N-formamides in the presence of PhSiH3 under metal-free and mild conditions. Lewis acid–base interaction between PhSiH3 and 18-crown-6 enhanced hydride-donating ability of the PhSiH3, thus facilitating the CO2 insertion into the Si–H bond. A positive correlation was observed between electron-donating ability and catalytic activity of the investigated crown ethers on CO2 reduction. Crown ethers thus represent a novel organocatalytic activation model for CO2 reduction, demonstrating an important alternative for transition-metal-based catalysts." @default.
- W4313649933 created "2023-01-07" @default.
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- W4313649933 date "2023-02-01" @default.
- W4313649933 modified "2023-09-25" @default.
- W4313649933 title "Crown ether as organocatalyst for reductive upgrading of CO2 to N-containing benzoheterocyclics and N-formamides" @default.
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- W4313649933 doi "https://doi.org/10.1016/j.jcat.2023.01.005" @default.
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