FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313650922> ?p ?o ?g. }

• W4313650922 endingPage "130928" @default.
• W4313650922 startingPage "130928" @default.
• W4313650922 abstract "In this work, we report the synthesis of non-cross-linked, spherical, hollow polymer nanocapsules of low dispersity in aqueous media. For this, well-defined diblock copolymer brushes, comprising a poly(methyl methacrylate) (PMMA) inner block and a poly(2-(dimethylamino)ethyl methacrylate) (PDMAEMA) outer block, were grown from the surface of silica spheres via surface-initiated atom transfer radical polymerization (SI-ATRP). Robust, hollow polymer nanocapsules were obtained in water following the etching of the inorganic core, with the hydrophobic PMMA block ensuring the structural integrity of the hollow colloids, while the hydrophilic PDMAEMA outer layer allowed their dispersion in aqueous media. The stability of the hollow polymer nanocapsules was found to require a minimum molecular weight and a high glass transition temperature of the solvent incompatible inner block, while the rigidity of the polymer shell was influenced by the length of the PMMA block as well as the grafting density of the polymer chains on the silica surface. The protocol for the synthesis of hollow polymer nanocapsules established in this work, overcomes the main challenges encountered to date in the preparation of polymer nanocapsules, related to low synthetic yields, polydispersity in size and the requirement to permanently cross-link the polymer chains to retain the capsule stability in the solvent medium. The nanocapsules reported in this study can be prepared at high yields, with tunable sizes and low dispersity in the absence of chemical cross-links." @default.
• W4313650922 created "2023-01-07" @default.
• W4313650922 creator A5011629017 @default.
• W4313650922 creator A5027499590 @default.
• W4313650922 creator A5036212114 @default.
• W4313650922 creator A5064216660 @default.
• W4313650922 creator A5082028779 @default.
• W4313650922 creator A5089271795 @default.
• W4313650922 date "2023-03-01" @default.
• W4313650922 modified "2023-10-16" @default.
• W4313650922 title "Non-cross-linked hollow polymer nanocapsules of controlled size and shell thickness" @default.
• W4313650922 cites W1966884594 @default.
• W4313650922 cites W1969206494 @default.
• W4313650922 cites W1971938312 @default.
• W4313650922 cites W1980084976 @default.
• W4313650922 cites W1983730706 @default.
• W4313650922 cites W1984233364 @default.
• W4313650922 cites W1989224177 @default.
• W4313650922 cites W1993204921 @default.
• W4313650922 cites W2002730188 @default.
• W4313650922 cites W2002879789 @default.
• W4313650922 cites W2006567243 @default.
• W4313650922 cites W2007524818 @default.
• W4313650922 cites W2008515873 @default.
• W4313650922 cites W2009274728 @default.
• W4313650922 cites W2024997770 @default.
• W4313650922 cites W2025293647 @default.
• W4313650922 cites W2031820392 @default.
• W4313650922 cites W2040677190 @default.
• W4313650922 cites W2042274498 @default.
• W4313650922 cites W2045531693 @default.
• W4313650922 cites W2064043342 @default.
• W4313650922 cites W2077857484 @default.
• W4313650922 cites W2077891697 @default.
• W4313650922 cites W2088198645 @default.
• W4313650922 cites W2089298600 @default.
• W4313650922 cites W2132128572 @default.
• W4313650922 cites W2159994190 @default.
• W4313650922 cites W2287793741 @default.
• W4313650922 cites W2313241247 @default.
• W4313650922 cites W2323007809 @default.
• W4313650922 cites W2346030527 @default.
• W4313650922 cites W2491653545 @default.
• W4313650922 cites W2581558788 @default.
• W4313650922 cites W2586821633 @default.
• W4313650922 cites W2769961614 @default.
• W4313650922 cites W2873951016 @default.
• W4313650922 cites W2894891418 @default.
• W4313650922 cites W2911511936 @default.
• W4313650922 cites W2994282213 @default.
• W4313650922 cites W3004842036 @default.
• W4313650922 cites W3014418912 @default.
• W4313650922 cites W4205626742 @default.
• W4313650922 cites W4255922903 @default.
• W4313650922 doi "https://doi.org/10.1016/j.colsurfa.2023.130928" @default.
• W4313650922 hasPublicationYear "2023" @default.
• W4313650922 type Work @default.
• W4313650922 citedByCount "1" @default.
• W4313650922 countsByYear W43136509222023 @default.
• W4313650922 crossrefType "journal-article" @default.
• W4313650922 hasAuthorship W4313650922A5011629017 @default.
• W4313650922 hasAuthorship W4313650922A5027499590 @default.
• W4313650922 hasAuthorship W4313650922A5036212114 @default.
• W4313650922 hasAuthorship W4313650922A5064216660 @default.
• W4313650922 hasAuthorship W4313650922A5082028779 @default.
• W4313650922 hasAuthorship W4313650922A5089271795 @default.
• W4313650922 hasConcept C11432220 @default.
• W4313650922 hasConcept C127413603 @default.
• W4313650922 hasConcept C132050475 @default.
• W4313650922 hasConcept C150539798 @default.
• W4313650922 hasConcept C155672457 @default.
• W4313650922 hasConcept C15920480 @default.
• W4313650922 hasConcept C159985019 @default.
• W4313650922 hasConcept C171250308 @default.
• W4313650922 hasConcept C188027245 @default.
• W4313650922 hasConcept C192562407 @default.
• W4313650922 hasConcept C204399865 @default.
• W4313650922 hasConcept C42360764 @default.
• W4313650922 hasConcept C44228677 @default.
• W4313650922 hasConcept C521977710 @default.
• W4313650922 hasConceptScore W4313650922C11432220 @default.
• W4313650922 hasConceptScore W4313650922C127413603 @default.
• W4313650922 hasConceptScore W4313650922C132050475 @default.
• W4313650922 hasConceptScore W4313650922C150539798 @default.
• W4313650922 hasConceptScore W4313650922C155672457 @default.
• W4313650922 hasConceptScore W4313650922C15920480 @default.
• W4313650922 hasConceptScore W4313650922C159985019 @default.
• W4313650922 hasConceptScore W4313650922C171250308 @default.
• W4313650922 hasConceptScore W4313650922C188027245 @default.
• W4313650922 hasConceptScore W4313650922C192562407 @default.
• W4313650922 hasConceptScore W4313650922C204399865 @default.
• W4313650922 hasConceptScore W4313650922C42360764 @default.
• W4313650922 hasConceptScore W4313650922C44228677 @default.
• W4313650922 hasConceptScore W4313650922C521977710 @default.
• W4313650922 hasLocation W43136509221 @default.
• W4313650922 hasOpenAccess W4313650922 @default.
• W4313650922 hasPrimaryLocation W43136509221 @default.
• W4313650922 hasRelatedWork W1486603386 @default.

• next