FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313652875> ?p ?o ?g. }

• W4313652875 endingPage "161453" @default.
• W4313652875 startingPage "161453" @default.
• W4313652875 abstract "Thermal plasma activation of CH4-CO2 reforming (CRM) to syngas under non-catalytic conditions is an efficient and clean technology for the large-scale utilization of hydrocarbon resources and the conversion of greenhouse gases. This study investigates the equilibrium state and transformation mechanism of a CRM reaction system activated by thermal plasma through experimental, thermodynamic, and kinetic analyses. The experimental results illustrated that the CO2 conversion rate and H2 selectivity showed a downward trend with an increase in the CO2/CH4 molar ratio, whereas the CH4 conversion rate and CO selectivity showed the opposite trend. When CO2/CH4 molar ratio was 6/4, the selectivity for CO and H2 increased to 87.0 % and 80.8 %, respectively. Excess CO2 promotes the partial oxidation of CH4 to eliminate carbon deposition, resulting in an H2/CO molar ratio value closer to 1. Thermodynamic results show that the thermal-plasma-initiated CRM reaction can reach thermodynamic equilibrium more easily than the conventional catalyzed reactions, achieving much higher feedstock gas conversion without carbon deposition. The kinetic results obtained from the PSR model revealed that CH4 and CO2 were cleaved to form free radicals at the instant of contact with the plasma flame. O, H, and other particles generated in the form of free radicals rapidly collided with each other and transformed into CO and H2, accelerating the reaction process. The results presented in this study will help reveal the transformation mechanism of the CRM reaction activated by thermal plasma under non-catalytic conditions and provide a new perspective for studying CRM reactions." @default.
• W4313652875 created "2023-01-07" @default.
• W4313652875 creator A5017439332 @default.
• W4313652875 creator A5017680984 @default.
• W4313652875 creator A5025918230 @default.
• W4313652875 creator A5029226343 @default.
• W4313652875 creator A5039868644 @default.
• W4313652875 creator A5043681789 @default.
• W4313652875 creator A5055431712 @default.
• W4313652875 creator A5071231716 @default.
• W4313652875 creator A5082585036 @default.
• W4313652875 creator A5002388831 @default.
• W4313652875 date "2023-03-01" @default.
• W4313652875 modified "2023-10-16" @default.
• W4313652875 title "Conversion mechanism of thermal plasma-enhanced CH4-CO2 reforming system to syngas under the non-catalytic conditions" @default.
• W4313652875 cites W1070771069 @default.
• W4313652875 cites W1970301710 @default.
• W4313652875 cites W1973997605 @default.
• W4313652875 cites W1995420139 @default.
• W4313652875 cites W2004089485 @default.
• W4313652875 cites W2009122420 @default.
• W4313652875 cites W2032794196 @default.
• W4313652875 cites W2044920956 @default.
• W4313652875 cites W2048192307 @default.
• W4313652875 cites W2053374809 @default.
• W4313652875 cites W2054797433 @default.
• W4313652875 cites W2055154696 @default.
• W4313652875 cites W2065322858 @default.
• W4313652875 cites W2106857129 @default.
• W4313652875 cites W2122976132 @default.
• W4313652875 cites W2150857061 @default.
• W4313652875 cites W2495387839 @default.
• W4313652875 cites W2575037983 @default.
• W4313652875 cites W2742630030 @default.
• W4313652875 cites W2755382456 @default.
• W4313652875 cites W2763613884 @default.
• W4313652875 cites W2771108955 @default.
• W4313652875 cites W2781640537 @default.
• W4313652875 cites W2782069180 @default.
• W4313652875 cites W2782966523 @default.
• W4313652875 cites W2785772560 @default.
• W4313652875 cites W2791362250 @default.
• W4313652875 cites W2792103689 @default.
• W4313652875 cites W2802751544 @default.
• W4313652875 cites W2810591411 @default.
• W4313652875 cites W2895539968 @default.
• W4313652875 cites W2896513053 @default.
• W4313652875 cites W2904055883 @default.
• W4313652875 cites W2917560602 @default.
• W4313652875 cites W2920909514 @default.
• W4313652875 cites W2921060918 @default.
• W4313652875 cites W2935557913 @default.
• W4313652875 cites W2957423701 @default.
• W4313652875 cites W2969774638 @default.
• W4313652875 cites W2975370615 @default.
• W4313652875 cites W2981085508 @default.
• W4313652875 cites W2997133422 @default.
• W4313652875 cites W2998320021 @default.
• W4313652875 cites W3004892652 @default.
• W4313652875 cites W3011709661 @default.
• W4313652875 cites W3014020388 @default.
• W4313652875 cites W3044414711 @default.
• W4313652875 cites W3049661901 @default.
• W4313652875 cites W3081748889 @default.
• W4313652875 cites W3081901802 @default.
• W4313652875 cites W3083034072 @default.
• W4313652875 cites W3088037942 @default.
• W4313652875 cites W3120421194 @default.
• W4313652875 cites W3122357612 @default.
• W4313652875 cites W3164447899 @default.
• W4313652875 cites W3202587172 @default.
• W4313652875 cites W3210864920 @default.
• W4313652875 cites W4200199709 @default.
• W4313652875 cites W4200361786 @default.
• W4313652875 cites W4206838415 @default.
• W4313652875 cites W4210607224 @default.
• W4313652875 cites W4210613516 @default.
• W4313652875 cites W4225115469 @default.
• W4313652875 cites W4283748153 @default.
• W4313652875 cites W99694429 @default.
• W4313652875 doi "https://doi.org/10.1016/j.scitotenv.2023.161453" @default.
• W4313652875 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36626987" @default.
• W4313652875 hasPublicationYear "2023" @default.
• W4313652875 type Work @default.
• W4313652875 citedByCount "0" @default.
• W4313652875 crossrefType "journal-article" @default.
• W4313652875 hasAuthorship W4313652875A5002388831 @default.
• W4313652875 hasAuthorship W4313652875A5017439332 @default.
• W4313652875 hasAuthorship W4313652875A5017680984 @default.
• W4313652875 hasAuthorship W4313652875A5025918230 @default.
• W4313652875 hasAuthorship W4313652875A5029226343 @default.
• W4313652875 hasAuthorship W4313652875A5039868644 @default.
• W4313652875 hasAuthorship W4313652875A5043681789 @default.
• W4313652875 hasAuthorship W4313652875A5055431712 @default.
• W4313652875 hasAuthorship W4313652875A5071231716 @default.
• W4313652875 hasAuthorship W4313652875A5082585036 @default.
• W4313652875 hasConcept C110686534 @default.
• W4313652875 hasConcept C118792377 @default.

• next