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- W4313689670 abstract "Abstract Six new triorganotin( iv ) complexes of 3-aminobenzoic acid-based Schiff bases, 3-(R′-CH═N)C 6 H 4 COOSnR 3 ( 1–6 ) (R′, R = 5-Br-2-HOC 6 H 3 , Ph ( 1 ); 3,5-Br 2 -2-HOC 6 H 2 , Ph ( 2 ); 4-NEt 2 -2-HOC 6 H 3 , Cy ( 3 ); 3-OCH 3 -2-HOC 6 H 3 , Cy ( 4 ); 2-HOC 10 H 6 , Ph ( 5 ); 2-HOC 10 H 6 , Cy ( 6 )), have been synthesized by the one-pot reaction of equimolar 3-aminobenzoic acid, substituted 2-hydroxybenzaldehyde (or 2-hydroxy-1-naphthaldehyde) and triorganotin( iv ) hydroxide, and characterized by elemental analysis, FT-IR, NMR spectroscopy, and X-ray single crystal diffraction. The NMR data ( 1 J ( 119 Sn– 13 C) and 119 Sn chemical shifts) suggested that these organotin( iv ) complexes are all four-coordinated in CDCl 3 solution. In the crystalline state, the tin atoms in 1–4 and 6 are four-coordinated and possess a distorted tetrahedral geometry. Complex 5 with crystalline solvents (CH 3 OH and CHCl 3 ) exhibits a zigzag chain, and the five coordination atoms on the tin atom are arranged in a trigonal bipyramidal geometry in which the carboxylate oxygen atom and the phenolic oxygen atom of the adjacent ligand occupy the axial positions. In all complexes, the 3-(arylmethyleneamino)benzoate ligands are coordinated with tin atoms in monodentate mode. Their cytotoxicity against two human cancer cell lines (A549 and HeLa), UV-Vis, and fluorescence have been determined, and the results reveal that complexes 1 – 6 have higher cytotoxicity than cisplatin and may be explored for potential blue luminescent materials." @default.
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- W4313689670 date "2022-01-01" @default.
- W4313689670 modified "2023-10-18" @default.
- W4313689670 title "Synthesis, structure, and cytotoxicity of some triorganotin(iv) complexes of 3-aminobenzoic acid-based Schiff bases" @default.
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- W4313689670 doi "https://doi.org/10.1515/mgmc-2022-0026" @default.
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