Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313830074> ?p ?o ?g. }
- W4313830074 endingPage "123151" @default.
- W4313830074 startingPage "123151" @default.
- W4313830074 abstract "The development of multi-site integrated nanomaterials with remarkable properties and their application to selective CO2 capture and utilization have attracted extensive research interest. In this study, several metalloporphyrin and triazine integrated nitrogen-rich frameworks (M ⊂ PPTFs; where “M” stands for metal) were constructed and structurally characterized. These frameworks’ tendency to adsorb CO2 and their catalytic performance in the conversion of CO2 to cyclic carbonates were then investigated. The cycloaddition between CO2 and epichlorohydrin to produce chloropropene carbonate was selected as model reaction to screen the various catalysts and optimize the reaction conditions. The recycling performance and substrate scope were also evaluated. Evidence indicated that Zn ⊂ PPTF15 has dual functions: CO2 adsorption and its synergistic conversion. The CO2 adsorption capacity reached values of 2315 μmol/g and 1883 μmol/g at 273 K and 298 K, respectively. Under conditions of synergistic catalysis with tetrabutylammonium bromide (TBAB), Zn ⊂ PPTF15 afforded 96% yield of chloropropene carbonate with 99% selectivity at 60 °C and 0.1 MPa CO2 pressure for 15 h. The catalytic conditions and activity were investigated by comparison with reported triazinyl-based polymers. Notably, the catalytic system also displayed satisfactory applicability to other epoxides. Furthermore, Zn ⊂ PPTF15 was easily recyclable and did not become deactivated after repeated use. Based on the multi-site structure of the catalyst and the experimental results, a possible mechanism was proposed for the cycloaddition reaction." @default.
- W4313830074 created "2023-01-09" @default.
- W4313830074 creator A5016678508 @default.
- W4313830074 creator A5038009686 @default.
- W4313830074 creator A5053194944 @default.
- W4313830074 creator A5056861386 @default.
- W4313830074 creator A5075478732 @default.
- W4313830074 creator A5082342946 @default.
- W4313830074 creator A5088192953 @default.
- W4313830074 date "2023-04-01" @default.
- W4313830074 modified "2023-10-14" @default.
- W4313830074 title "Metalloporphyrin and triazine integrated nitrogen-rich frameworks as high-performance platform for CO2 adsorption and conversion under ambient pressure" @default.
- W4313830074 cites W2057476456 @default.
- W4313830074 cites W2059290758 @default.
- W4313830074 cites W2103247835 @default.
- W4313830074 cites W2104015519 @default.
- W4313830074 cites W2138133039 @default.
- W4313830074 cites W2240516458 @default.
- W4313830074 cites W2321797008 @default.
- W4313830074 cites W2516989235 @default.
- W4313830074 cites W2587635451 @default.
- W4313830074 cites W2589776373 @default.
- W4313830074 cites W2597966662 @default.
- W4313830074 cites W2609333415 @default.
- W4313830074 cites W2754640533 @default.
- W4313830074 cites W2778959682 @default.
- W4313830074 cites W2779828134 @default.
- W4313830074 cites W2783302098 @default.
- W4313830074 cites W2791915426 @default.
- W4313830074 cites W2796193628 @default.
- W4313830074 cites W2798004356 @default.
- W4313830074 cites W2804507472 @default.
- W4313830074 cites W2902849156 @default.
- W4313830074 cites W2903329849 @default.
- W4313830074 cites W2903657888 @default.
- W4313830074 cites W2908169377 @default.
- W4313830074 cites W2943474137 @default.
- W4313830074 cites W2963363541 @default.
- W4313830074 cites W2963408627 @default.
- W4313830074 cites W2964643219 @default.
- W4313830074 cites W2969238304 @default.
- W4313830074 cites W2969249444 @default.
- W4313830074 cites W2981291945 @default.
- W4313830074 cites W2988232688 @default.
- W4313830074 cites W2992875998 @default.
- W4313830074 cites W2997043792 @default.
- W4313830074 cites W2998024784 @default.
- W4313830074 cites W2999968933 @default.
- W4313830074 cites W3003051421 @default.
- W4313830074 cites W3012438363 @default.
- W4313830074 cites W3083785130 @default.
- W4313830074 cites W3090668976 @default.
- W4313830074 cites W3102292033 @default.
- W4313830074 cites W3110343376 @default.
- W4313830074 cites W3134404452 @default.
- W4313830074 cites W3160923932 @default.
- W4313830074 cites W3205838061 @default.
- W4313830074 cites W3206516853 @default.
- W4313830074 cites W3213781658 @default.
- W4313830074 cites W4205644045 @default.
- W4313830074 cites W4210370063 @default.
- W4313830074 cites W4239167683 @default.
- W4313830074 cites W4293560483 @default.
- W4313830074 cites W4295021985 @default.
- W4313830074 cites W4376848735 @default.
- W4313830074 doi "https://doi.org/10.1016/j.seppur.2023.123151" @default.
- W4313830074 hasPublicationYear "2023" @default.
- W4313830074 type Work @default.
- W4313830074 citedByCount "9" @default.
- W4313830074 countsByYear W43138300742023 @default.
- W4313830074 crossrefType "journal-article" @default.
- W4313830074 hasAuthorship W4313830074A5016678508 @default.
- W4313830074 hasAuthorship W4313830074A5038009686 @default.
- W4313830074 hasAuthorship W4313830074A5053194944 @default.
- W4313830074 hasAuthorship W4313830074A5056861386 @default.
- W4313830074 hasAuthorship W4313830074A5075478732 @default.
- W4313830074 hasAuthorship W4313830074A5082342946 @default.
- W4313830074 hasAuthorship W4313830074A5088192953 @default.
- W4313830074 hasConcept C118792377 @default.
- W4313830074 hasConcept C127413603 @default.
- W4313830074 hasConcept C129652920 @default.
- W4313830074 hasConcept C150394285 @default.
- W4313830074 hasConcept C161790260 @default.
- W4313830074 hasConcept C178790620 @default.
- W4313830074 hasConcept C179104552 @default.
- W4313830074 hasConcept C185592680 @default.
- W4313830074 hasConcept C188027245 @default.
- W4313830074 hasConcept C2776303721 @default.
- W4313830074 hasConcept C2778925040 @default.
- W4313830074 hasConcept C2779664164 @default.
- W4313830074 hasConcept C42360764 @default.
- W4313830074 hasConcept C537208039 @default.
- W4313830074 hasConceptScore W4313830074C118792377 @default.
- W4313830074 hasConceptScore W4313830074C127413603 @default.
- W4313830074 hasConceptScore W4313830074C129652920 @default.
- W4313830074 hasConceptScore W4313830074C150394285 @default.
- W4313830074 hasConceptScore W4313830074C161790260 @default.
- W4313830074 hasConceptScore W4313830074C178790620 @default.