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- W4313837459 abstract "The formal redox potential can be evaluated from Nernst plots without background absorbance correction. Electronic absorption spectra with higher-order derivative conversions effectively eliminate wavelength-independent absorption. As an example, thin-layer spectroelectrochemical measurements were performed on water-soluble ferrocenecarboxylic acid in a buffer solution. Although the potential-dependent absorption spectra did not have isosbestic points, common crossing points appeared in the higher-order derivative spectra, indicating that the redox reaction was unitary." @default.
- W4313837459 created "2023-01-09" @default.
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- W4313837459 date "2023-02-01" @default.
- W4313837459 modified "2023-10-14" @default.
- W4313837459 title "Evaluation of formal redox potential from Nernstian plots using higher-order derivative spectra with no background correction" @default.
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- W4313837459 doi "https://doi.org/10.1016/j.jelechem.2023.117151" @default.
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