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• W4313857601 endingPage "1209" @default.
• W4313857601 startingPage "1202" @default.
• W4313857601 abstract "The excited-state manipulation of the phosphorescent iridium(III) complexes plays a vital role in their photofunctional applications. The development of the molecular design strategy promotes the creative findings of novel iridium(III) complexes. The current molecular design strategies for iridium(III) complexes mainly depend on the selective cyclometalation of the ligands with the iridium(III) ion, which is governed by the steric hindrance of the ligand during the cyclometalation. Herein, a new molecular design strategy (i.e., random cyclometalation strategy) is proposed for the effective excited-state manipulation of phosphorescent cyclometalated iridium(III) complexes. Two series of new and separable methoxyl-functionalized isomeric iridium(III) complexes are accessed by a one-pot synthesis via random cyclometalation, resulting in a dramatic tuning of the phosphorescence peak wavelength (∼57 nm) and electrochemical properties attributed to the high sensitivity of their excited states to the position of the methoxyl group. These iridium(III) complexes show intense phosphorescence ranging from the yellow (567 nm) to the deep-red (634 nm) color with high photoluminescence quantum yields of up to 0.99. Two deep-red emissive iridium(III) complexes with short decay lifetimes are further utilized as triplet emitters to afford efficient solution-processed electroluminescence with reduced efficiency roll-offs." @default.
• W4313857601 created "2023-01-10" @default.
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• W4313857601 date "2023-01-09" @default.
• W4313857601 modified "2023-10-16" @default.
• W4313857601 title "One-Pot Synthesis of Acetylacetonate-Based Isomeric Phosphorescent Cyclometalated Iridium(III) Complexes via Random Cyclometalation: A Strategy for Excited-State Manipulation" @default.
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• W4313857601 doi "https://doi.org/10.1021/acs.inorgchem.2c03597" @default.
• W4313857601 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36622043" @default.
• W4313857601 hasPublicationYear "2023" @default.
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