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- W4313890760 abstract "The direct and rapid determination of trace cobalt ion (Co2+) in the electrolyte of zinc smelting plants is urgently needed but is impeded by the severe interference of extremely high-concentration zinc ions in the solution. Herein, colorimetric detection of Co2+ by the polyvinylpyrrolidone functionalized silver nanoparticles (PVP-AgNPs) is realized in solutions with the Zn/Co ratio being high, up to (0.8–5) × 104, which is located within the ratio range in industrial solution. The high concentration of Zn2+ induces a strong attenuation of Co2+-related signals in ultraviolet-visible (UV-vis) extinction spectra; nevertheless, a good linear range for detecting 1–6 mg/L Co2+ in 50 g/L Zn2+ solution is still acquired. The strong anti-interference toward other metal ions and the mechanism understanding for trace Co2+ detection in such a high-concentration Zn2+ solution are also revealed by systematic analysis techniques. The results extend the AgNPs as colorimetric sensors to industrial solutions, providing a new strategy for detecting trace-metal ions in industrial plants." @default.
- W4313890760 created "2023-01-10" @default.
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- W4313890760 date "2023-01-06" @default.
- W4313890760 modified "2023-10-01" @default.
- W4313890760 title "Extending Ag Nanoparticles as Colorimetric Sensor to Industrial Zinc Electrolyte for Cobalt Ion Detection" @default.
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- W4313890760 doi "https://doi.org/10.3390/molecules28020592" @default.
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