Matches in SemOpenAlex for { <https://semopenalex.org/work/W4313897515> ?p ?o ?g. }
- W4313897515 endingPage "112123" @default.
- W4313897515 startingPage "112123" @default.
- W4313897515 abstract "The FeIVO complexes of bispidines (3,7-diazabicyclo[3.3.1]nonane derivatives) are known to be highly reactive oxidants – with the tetradentate bispidine, the so far most reactive ferryl complex has been reported and two isomeric pentadentate ligands also lead to very reactive high-valent oxidants. With a series of 4 new bispidine derivatives we now try to address the question why the bispidine scaffold in general leads to very reactive oxidants and how this can be tuned by ligand modifications. The study is based on a full structural, spectroscopic and electrochemical analysis of the iron(II) precursors, spectroscopic data of the iron(IV)-oxido complexes, a kinetic analysis of the stoichiometric oxidation of thioanisole by five different bispidine‑iron(IV)-oxido complexes and on product analyses of reactions by the five ferryl oxidants with thioanisole, β-methylstyrene and cis-stilbene as substrates." @default.
- W4313897515 created "2023-01-10" @default.
- W4313897515 creator A5003430775 @default.
- W4313897515 creator A5018905339 @default.
- W4313897515 creator A5043797274 @default.
- W4313897515 creator A5080929915 @default.
- W4313897515 creator A5081835575 @default.
- W4313897515 date "2023-04-01" @default.
- W4313897515 modified "2023-10-17" @default.
- W4313897515 title "Reactivities of iron(IV)-oxido compounds with pentadentate bispidine ligands" @default.
- W4313897515 cites W1792646340 @default.
- W4313897515 cites W1957117059 @default.
- W4313897515 cites W1967314547 @default.
- W4313897515 cites W1974842081 @default.
- W4313897515 cites W1976205221 @default.
- W4313897515 cites W1977750235 @default.
- W4313897515 cites W1983412406 @default.
- W4313897515 cites W1986531390 @default.
- W4313897515 cites W1992097289 @default.
- W4313897515 cites W1997259321 @default.
- W4313897515 cites W1999009446 @default.
- W4313897515 cites W1999582957 @default.
- W4313897515 cites W2002384424 @default.
- W4313897515 cites W2005927376 @default.
- W4313897515 cites W2009317764 @default.
- W4313897515 cites W2011890891 @default.
- W4313897515 cites W2012090737 @default.
- W4313897515 cites W2014926653 @default.
- W4313897515 cites W2021440490 @default.
- W4313897515 cites W2025159610 @default.
- W4313897515 cites W2026499868 @default.
- W4313897515 cites W2027530360 @default.
- W4313897515 cites W2029556357 @default.
- W4313897515 cites W2029630162 @default.
- W4313897515 cites W2033030973 @default.
- W4313897515 cites W2034796508 @default.
- W4313897515 cites W2042325641 @default.
- W4313897515 cites W2046414723 @default.
- W4313897515 cites W2049616753 @default.
- W4313897515 cites W2054950973 @default.
- W4313897515 cites W2055075258 @default.
- W4313897515 cites W2064924209 @default.
- W4313897515 cites W2068128923 @default.
- W4313897515 cites W2068788602 @default.
- W4313897515 cites W2069953538 @default.
- W4313897515 cites W2073490466 @default.
- W4313897515 cites W2077749836 @default.
- W4313897515 cites W2077898401 @default.
- W4313897515 cites W2080447728 @default.
- W4313897515 cites W2090245920 @default.
- W4313897515 cites W2097532911 @default.
- W4313897515 cites W2105067416 @default.
- W4313897515 cites W2107743024 @default.
- W4313897515 cites W2111071894 @default.
- W4313897515 cites W2123265733 @default.
- W4313897515 cites W2134077470 @default.
- W4313897515 cites W2139134933 @default.
- W4313897515 cites W2143753629 @default.
- W4313897515 cites W2145709112 @default.
- W4313897515 cites W2156396299 @default.
- W4313897515 cites W2156722259 @default.
- W4313897515 cites W2159843762 @default.
- W4313897515 cites W2164102479 @default.
- W4313897515 cites W2279103949 @default.
- W4313897515 cites W2320321473 @default.
- W4313897515 cites W2321292804 @default.
- W4313897515 cites W2335733462 @default.
- W4313897515 cites W2493615870 @default.
- W4313897515 cites W2560843697 @default.
- W4313897515 cites W2616931628 @default.
- W4313897515 cites W2622436115 @default.
- W4313897515 cites W2758582642 @default.
- W4313897515 cites W2781813451 @default.
- W4313897515 cites W2799530527 @default.
- W4313897515 cites W2893669076 @default.
- W4313897515 cites W2947478297 @default.
- W4313897515 cites W3028768470 @default.
- W4313897515 cites W3096527160 @default.
- W4313897515 cites W3151186751 @default.
- W4313897515 cites W3173073007 @default.
- W4313897515 cites W3197209255 @default.
- W4313897515 cites W3212147401 @default.
- W4313897515 cites W4240807757 @default.
- W4313897515 cites W4245957997 @default.
- W4313897515 cites W4308857153 @default.
- W4313897515 doi "https://doi.org/10.1016/j.jinorgbio.2023.112123" @default.
- W4313897515 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36701984" @default.
- W4313897515 hasPublicationYear "2023" @default.
- W4313897515 type Work @default.
- W4313897515 citedByCount "1" @default.
- W4313897515 countsByYear W43138975152023 @default.
- W4313897515 crossrefType "journal-article" @default.
- W4313897515 hasAuthorship W4313897515A5003430775 @default.
- W4313897515 hasAuthorship W4313897515A5018905339 @default.
- W4313897515 hasAuthorship W4313897515A5043797274 @default.
- W4313897515 hasAuthorship W4313897515A5080929915 @default.
- W4313897515 hasAuthorship W4313897515A5081835575 @default.
- W4313897515 hasConcept C116569031 @default.